For \(\ell=1\), the operators that measure the three components of angular momentum in matrix notation are given by: \begin{align} L_x&=\frac{\hbar}{\sqrt{2}}\left( \begin{matrix} 0&1&0\\ 1&0&1\\ 0&1&0 \end{matrix} \right)\\ L_y&=\frac{\hbar}{\sqrt{2}}\left( \begin{matrix} 0&-i&0\\ i&0&-i\\ 0&i&0 \end{matrix} \right)\\ L_z&=\;\;\;\hbar\left( \begin{matrix} 1&0&0\\ 0&0&0\\ 0&0&-1 \end{matrix} \right) \end{align}
Show that:
- Find the commutator of \(L_x\) and \(L_y\).
- Find the matrix representation of \(L^2=L_x^2+L_y^2+L_z^2\).
- Find the matrix representations of the raising and lowering operators \(L_{\pm}=L_x\pm iL_y\). (Notice that \(L_{\pm}\) are NOT Hermitian and therefore cannot represent observables. They are used as a tool to build one quantum state from another.)
- Show that \([L_z, L_{\pm}]=\lambda L_{\pm}\). Find \(\lambda\). Interpret this expression as an eigenvalue equation. What is the operator?
- Let \(L_{+}\) act on the following three states given in matrix representation. \begin{equation} \left|{1,1}\right\rangle =\left( \begin{matrix} 1\\0\\0 \end{matrix} \right)\qquad \left|{1,0}\right\rangle =\left( \begin{matrix} 0\\1\\0 \end{matrix} \right)\qquad \left|{1,-1}\right\rangle =\left( \begin{matrix} 0\\0\\1 \end{matrix} \right) \end{equation} Why is \(L_{+}\) called a “raising operator”?
assignment Homework
\(z_1=i\),
keyboard Computational Activity
120 min.
quantum mechanics operator matrix element particle in a box eigenfunction
Students find matrix elements of the position operator \(\hat x\) in a sinusoidal basis. This allows them to express this operator as a matrix, which they can then numerically diagonalize and visualize the eigenfunctions.group Small Group Activity
10 min.
group Small Group Activity
30 min.
assignment Homework
assignment Homework
Writing an operator in matrix notation in its own basis is easy: it is diagonal with the eigenvalues on the diagonal.
What if I want to calculate the matrix elements using a different basis??
The eigenvalue equation tells me what happens when an operator acts on its own eigenstate. For example: \(\hat{S}_y\left|{\pm}\right\rangle _y=\pm\frac{\hbar}{2}\left|{\pm}\right\rangle _y\)
In Dirac bra-ket notation, to know what an operator does to a ket, I needs to write the ket in the basis that is the eigenstates of the operator (in order to use the eigenvalue equation.)
One way to do this to stick completeness relationships into the braket: \begin{eqnarray*} \left\langle {+}\right|\hat{S_y}\left|{+}\right\rangle = \left\langle {+}\right|(I)\hat{S_y}(I)\left|{+}\right\rangle \end{eqnarray*}
where \(I\) is the identity operator: \(I=\color{blue}{\left|{+}\right\rangle _{yy}\left\langle {+}\right|}\;+\;\color{blue}{\left|{-}\right\rangle _{yy}\left\langle {-}\right|}\). This effectively rewrite the \(\left|{+}\right\rangle \) in the \(\left|{\pm}\right\rangle _y\) basis.
Find the top row matrix elements of the operator \(\hat{S}_y\) in the \(S_z\) basis by inserting completeness relations into the brakets. (The answer is already on the Spins Reference Sheet, but I want you do demonstrate the calculation.)
accessibility_new Kinesthetic
10 min.
Quantum State Vectors Complex Numbers Spin 1/2 Arms Representation
Students, working in pairs, use their left arms to represent each component in a two-state quantum spin 1/2 system. Reinforces the idea that quantum states are complex valued vectors. Students make connections between Dirac, matrix, and Arms representation.keyboard Computational Activity
120 min.
finite difference hamiltonian quantum mechanics particle in a box eigenfunctions
Students implement a finite-difference approximation for the kinetic energy operator as a matrix, and then usenumpy
to solve for eigenvalues and eigenstates, which they visualize.
assignment Homework
The following are 3 different representations for the \(\textbf{same}\) state on a quantum ring for \(r_0=1\) \begin{equation} \left|{\Phi_a}\right\rangle = i\sqrt{\frac{ 2}{12}}\left|{3}\right\rangle - \sqrt{\frac{ 1}{12}}\left|{1}\right\rangle +\sqrt{\frac{ 3}{12}}e^{i\frac{\pi}{4}}\left|{0}\right\rangle -i\sqrt{\frac{ 2}{ 12}}\left|{-1}\right\rangle +\sqrt{\frac{ 4}{12}}\left|{-3}\right\rangle \end{equation} \begin{equation} \left| \Phi_b\right\rangle \doteq \left( \begin{matrix} \vdots \\ i\sqrt{\frac{ 2}{12}}\\ 0 \\ -\sqrt{\frac{ 1}{12}} \\ \sqrt{\frac{ 3}{12}}e^{i\frac{\pi}{4}} \\ -i\sqrt{\frac{ 2}{12}}\\ 0 \\ \sqrt{\frac{4}{12} }\\ \vdots \end{matrix}\right) \begin{matrix} \leftarrow m=0 \end{matrix} \end{equation} \begin{equation} \Phi_c(\phi) \doteq \sqrt{\frac{1}{24 \pi}} \left( i\sqrt{2}e^{i 3 \phi} -e^{i\phi} +\sqrt{3}e^{i\frac{\pi}{4}} -i \sqrt{2} e^{-i\phi} + \sqrt{4}e^{-i 3 \phi} \right) \end{equation}
If you measured the energy of the state to be \(\frac{9}{2}\frac{\hbar^2}{I}\), what would the state of the particle be immediately after the measurement is made?
group Small Group Activity
30 min.
central forces quantum mechanics eigenstates eigenvalues quantum measurements angular momentum energy hermitian operators probability superposition representations notations degeneracy
Students calculate probabilities for a particle on a ring using three different notations: Dirac bra-ket, matrix, and wave function. After calculating the angular momentum and energy measurement probabilities, students compare their calculation methods for notation.