Students use a PhET to explore properties of the Planck distribution.
Google “phet blackbody spectrum”' and open the simulation.
face Lecture
5 min.
assignment Homework
assignment Homework
In carbon monoxide poisoning the CO replaces the \(\textsf{O}_{2}\) adsorbed on hemoglobin (\(\text{Hb}\)) molecules in the blood. To show the effect, consider a model for which each adsorption site on a heme may be vacant or may be occupied either with energy \(\varepsilon_A\) by one molecule \(\textsf{O}_{2}\) or with energy \(\varepsilon_B\) by one molecule CO. Let \(N\) fixed heme sites be in equilibrium with \(\textsf{O}_{2}\) and CO in the gas phases at concentrations such that the activities are \(\lambda(\text{O}_2) = 1\times 10^{-5}\) and \(\lambda(\text{CO}) = 1\times 10^{-7}\), all at body temperature \(37^\circ\text{C}\). Neglect any spin multiplicity factors.
First consider the system in the absence of CO. Evaluate \(\varepsilon_A\) such that 90 percent of the \(\text{Hb}\) sites are occupied by \(\textsf{O}_{2}\). Express the answer in eV per \(\textsf{O}_{2}\).
Now admit the CO under the specified conditions. Fine \(\varepsilon_B\) such that only 10% of the Hb sites are occupied by \(\textsf{O}_{2}\).
group Small Group Activity
5 min.
assignment Homework
group Small Group Activity
10 min.
group Small Group Activity
10 min.
face Lecture
120 min.
chemical potential Gibbs distribution grand canonical ensemble statistical mechanics
These notes from the fifth week of Thermal and Statistical Physics cover the grand canonical ensemble. They include several small group activities.group Small Group Activity
30 min.
assignment Homework
On the following diagrams, mark both \(\theta\) and \(\sin\theta\) for \(\theta_1=\frac{5\pi}{6}\) and \(\theta_2=\frac{7\pi}{6}\). Write one to three sentences about how these two representations are related to each other. (For example, see: this PHET)