Consider a three-state system with energies \((-\epsilon,0,\epsilon)\).

1. At infinite temperature, what are the probabilities of the three states being occupied? What is the internal energy \(U\)? What is the entropy \(S\)?
2. At very low temperature, what are the three probabilities?
3. What are the three probabilities at zero temperature? What is the internal energy \(U\)? What is the entropy \(S\)?
4. What happens to the probabilities if you allow the temperature to be negative?

These notes, from the third week of https://paradigms.oregonstate.edu/courses/ph441 cover the canonical ensemble and Helmholtz free energy. They include a number of small group activities.

The goal of this problem is to show that once we have maximized the entropy and found the microstate probabilities in terms of a Lagrange multiplier \(\beta\), we can prove that \(\beta=\frac1{kT}\) based on the statistical definitions of energy and entropy and the thermodynamic definition of temperature embodied in the thermodynamic identity.

The internal energy and entropy are each defined as a weighted average over microstates: \begin{align} U &= \sum_i E_i P_i & S &= -k_B\sum_i P_i \ln P_i \end{align}: We saw in clase that the probability of each microstate can be given in terms of a Lagrange multiplier \(\beta\) as \begin{align} P_i &= \frac{e^{-\beta E_i}}{Z} & Z &= \sum_i e^{-\beta E_i} \end{align} Put these probabilities into the above weighted averages in order to relate \(U\) and \(S\) to \(\beta\). Then make use of the thermodynamic identity \begin{align} dU = TdS - pdV \end{align} to show that \(\beta = \frac1{kT}\).

Students use Mathematica to visualize the probability density distribution for the hydrogen atom orbitals with the option to vary the values of \(n\), \(\ell\), and \(m\).

This activity reinforces the strategies students have been practicing on each system by letting them create their own matrix operators and columns on the hydrogen atom and do some calculations with them.

In this small group activity, students work out the steady state temperature of an object absorbing and emitting blackbody radiation.

A black (nonreflective) sheet of metal at high temperature \(T_h\) is parallel to a cold black sheet of metal at temperature \(T_c\). Each sheet has an area \(A\) which is much greater than the distance between them. The sheets are in vacuum, so energy can only be transferred by radiation.

1. Solve for the net power transferred between the two sheets.

2. A third black metal sheet is inserted between the other two and is allowed to come to a steady state temperature \(T_m\). Find the temperature of the middle sheet, and solve for the new net power transferred between the hot and cold sheets. This is the principle of the heat shield, and is part of how the James Web telescope shield works.

3. Optional: Find the power through an \(N\)-layer sandwich.

Consider a system of fixed volume in thermal contact with a resevoir. Show that the mean square fluctuations in the energy of the system is \begin{equation} \left<\left(\varepsilon-\langle\varepsilon\rangle\right)^2\right> = k_BT^2\left(\frac{\partial U}{\partial T}\right)_{V} \end{equation} Here \(U\) is the conventional symbol for \(\langle\varepsilon\rangle\). Hint: Use the partition function \(Z\) to relate \(\left(\frac{\partial U}{\partial T}\right)_V\) to the mean square fluctuation. Also, multiply out the term \((\cdots)^2\).

In this activity, students apply the Stefan-Boltzmann equation and the principle of energy balance in steady state to find the steady state temperature of a black object in near-Earth orbit.

This small group activity has students reasoning about how the Planck distribution shifts when the temperature is doubled. This leads to a qualitative argument for the Stefan-Boltzmann law.

Students are asked to find eigenvalues, probabilities, and expectation values for \(H\), \(L^2\), and \(L_z\) for a superposition of \(\vert n \ell m \rangle\) states. This can be done on small whiteboards or with the students working in groups on large whiteboards.

Students then work together in small groups to find the matrices that correspond to \(H\), \(L^2\), and \(L_z\) and to redo \(\langle E\rangle\) in matrix notation.

Students see probability density for eigenstates and linear combinations of eigenstates for a particle on a ring. The three visual representations: standard position vs probability density plot, a ring with colormapping, and cylindrical plot with height and colormapping, are also animated to visualize time-evolution.

A beam of spin-\(\frac{1}{2}\) particles is prepared in the initial state \[ \left\vert \psi\right\rangle = \sqrt{\frac{2}{5}}\; |+\rangle_x - \sqrt{\frac{3}{5}}\; |-\rangle_x \](Note: this state is written in the \(S_x\) basis!)

1. What are the possible results of a measurement of \(S_x\), with what probabilities?

2. Repeat part a for measurements of \(S_z\).

3. Suppose you start with a particle in the state given above, measure \(S_x\), and happen to get \(+\hbar /2\). You then take that same particle and measure \(S_z\). What are the possible results and with what probability would you measure each possible result?

The goal of this problem is to show that once we have maximized the entropy and found the microstate probabilities in terms of a Lagrange multiplier \(\beta\), we can prove that \(\beta=\frac1{kT}\) based on the statistical definitions of energy and entropy and the thermodynamic definition of temperature embodied in the thermodynamic identity.

The internal energy and entropy are each defined as a weighted average over microstates: \begin{align} U &= \sum_i E_i P_i & S &= -k_B\sum_i P_i \ln P_i \end{align} We saw in clase that the probability of each microstate can be given in terms of a Lagrange multiplier \(\beta\) as \begin{align} P_i &= \frac{e^{-\beta E_i}}{Z} & Z &= \sum_i e^{-\beta E_i} \end{align} Put these probabilities into the above weighted averages in order to relate \(U\) and \(S\) to \(\beta\). Then make use of the thermodynamic identity \begin{align} dU = TdS - pdV \end{align} to show that \(\beta = \frac1{kT}\).

Students calculate probabilities for a particle on a ring whose wavefunction is not easily separated into eigenstates by inspection. To find the energy, angular momentum, and position probabilities, students perform integrations with the wavefunction or decompose the wavefunction into a superposition of eigenfunctions.

Students calculate probabilities for a particle on a ring using three different notations: Dirac bra-ket, matrix, and wave function. After calculating the angular momentum and energy measurement probabilities, students compare their calculation methods for notation.

Students calculate probabilities for energy, angular momentum, and position as a function of time for an initial state that is a linear combination of energy/angular momentum eigenstates for a particle confined to a ring written in bra-ket notation. This activity helps students build an understanding of when they can expect a quantity to depend on time and to give them more practice moving between representations.

In this small group activity, students solve for the time dependence of two quantum spin 1/2 particles under the influence of a Hamiltonian. Students determine, given a Hamiltonian, which states are stationary and under what circumstances measurement probabilities do change with time.

Students compute probabilities and averages given a probability density in one dimension. This activity serves as a soft introduction to the particle in a box, introducing all the concepts that are needed.

Students become acquainted with the Spins Simulations of Stern-Gerlach Experiments and record measurement probabilities of spin components for a spin-1/2 system. Students start developing intuitions for the results of quantum measurements for this system.

This activity lets students explore translating a wavefunction that isn't obviously made up of eigenstates at first glance into ket and matrix form. Then students explore wave functions, probabilities in a region, expectation values, and what wavefunctions can tell you about measurements of \(L_z\).