face Lecture

30 min.

Compare & Contrast Kets & Wavefunctions

Bra-Ket Notations Wavefunction Notation Completeness Relations Probability Probability Density

Completeness Relations

In this lecture, the instructor guides a discussion about translating between bra-ket notation and wavefunction notation for quantum systems.

group Small Group Activity

30 min.

\(|\pm\rangle\) Forms an Orthonormal Basis
Quantum Fundamentals 2023 (3 years)

Cartesian Basis $S_z$ basis completeness normalization orthogonality basis

Completeness Relations

Student explore the properties of an orthonormal basis using the Cartesian and \(S_z\) bases as examples.

assignment Homework

Dimensional Analysis of Kets
dirac notation dimensions probability completeness relations

Completeness Relations

  1. \(\left\langle {\Psi}\middle|{\Psi}\right\rangle =1\) Identify and discuss the dimensions of \(\left|{\Psi}\right\rangle \).
  2. For a spin \(\frac{1}{2}\) system, \(\left\langle {\Psi}\middle|{+}\right\rangle \left\langle {+}\middle|{\Psi}\right\rangle + \left\langle {\Psi}\middle|{-}\right\rangle \left\langle {-}\middle|{\Psi}\right\rangle =1\). Identify and discuss the dimensions of \(\left|{+}\right\rangle \) and \(\left|{-}\right\rangle \).
  3. In the position basis \(\int \left\langle {\Psi}\middle|{x}\right\rangle \left\langle {x}\middle|{\Psi}\right\rangle dx = 1\). Identify and discuss the dimesions of \(\left|{x}\right\rangle \).

group Small Group Activity

30 min.

Hydrogen Probabilities in Matrix Notation
Central Forces 2023 (2 years)

group Small Group Activity

60 min.

Going from Spin States to Wavefunctions
Quantum Fundamentals 2023 (2 years)

Wavefunctions quantum states probability amplitude histograms matrix notation of quantum states Arms representation

Arms Sequence for Complex Numbers and Quantum States

Completeness Relations

Students review using the Arms representation to represent states for discrete quantum systems and connecting the Arms representation to histogram and matrix representation. The student then extend the Arms representation to begin exploring the continuous position basis.

assignment Homework

Quantum Particle in a 2-D Box
Central Forces 2023 (4 years) You know that the normalized spatial eigenfunctions for a particle in a 1-D box of length \(L\) are \(\sqrt{\frac{2}{L}}\sin{\frac{n\pi x}{L}}\). If you want the eigenfunctions for a particle in a 2-D box, then you just multiply together the eigenfunctions for a 1-D box in each direction. (This is what the separation of variables procedure tells you to do.)
  1. Find the normalized eigenfunctions for a particle in a 2-D box with sides of length \(L_x\) in the \(x\)-direction and length \(L_y\) in the \(y\)-direction.
  2. Find the Hamiltonian for a 2-D box and show that your eigenstates are indeed eigenstates and find a formula for the possible energies
  3. Any sufficiently smooth spatial wave function inside a 2-D box can be expanded in a double sum of the product wave functions, i.e. \begin{equation} \psi(x,y)=\sum_{n=1}^{\infty}\sum_{m=1}^{\infty}\, c_{nm}\; \hbox{eigenfunction}_n(x)\;\hbox{eigenfunction}_m(y) \end{equation} Using your expressions from part (a) above, write out all the terms in this sum out to \(n=3\), \(m=3\). Arrange the terms, conventionally, in terms of increasing energy.

    You may find it easier to work in bra/ket notation: \begin{align*} \left|{\psi}\right\rangle &=\sum_{n=1}^{\infty}\sum_{m=1}^{\infty}\, c_{nm}\left|{n}\right\rangle \left|{m}\right\rangle \\ &=\sum_{n=1}^{\infty}\sum_{m=1}^{\infty}\, c_{nm}\left|{nm}\right\rangle \end{align*}

  4. Find a formula for the \(c_{nm}\)s in part (b). Find the formula first in bra ket notation and then rewrite it in wave function notation.

assignment Homework

Visualization of Wave Functions on a Ring
Central Forces 2023 (3 years) Using either this Geogebra applet or this Mathematica notebook, explore the wave functions on a ring. (Note: The Geogebra applet may be a little easier to use and understand and is accessible if you don't have access to Mathematica, but it is more limited in the wave functions that you can represent. Also, the animation is pretty jumpy in some browsers, especially Firefox. Imagine that the motion is smooth.)
  1. Look at graphs of the following states \begin{align} \Phi_1(\phi)&=\frac{1}{\sqrt{2}}(\left|{2}\right\rangle +\left|{-2}\right\rangle )\\ \Phi_2(\phi)&=\frac{1}{\sqrt{2}}(\left|{2}\right\rangle -\left|{-2}\right\rangle )\\ \Phi_3(\phi)&=\frac{1}{\sqrt{2}}(\left|{2}\right\rangle +i\left|{-2}\right\rangle ) \end{align} Write a short description of how these states differ from each other.
  2. Find a state for which the probability density does not depend on time. Write the state in both ket and wave function notation. These are called stationary states. Generalize your result to give a characterization of the set of all possible states that are stationary states.
  3. Find a state that is right-moving. Write the state in both ket and wave function notation. Generalize your result to give a characterization of the set of all possible states that are right-moving.
  4. Find a state that is a standing wave. Write the state in both ket and wave function notation. Generalize your result to give a characterization of the set of all possible states that are standing waves.

group Small Group Activity

30 min.

Energy and Angular Momentum for a Quantum Particle on a Ring

central forces quantum mechanics eigenstates eigenvalues quantum measurements angular momentum energy hermitian operators probability superposition representations notations degeneracy

Quantum Ring Sequence

Students calculate probabilities for a particle on a ring using three different notations: Dirac bra-ket, matrix, and wave function. After calculating the angular momentum and energy measurement probabilities, students compare their calculation methods for notation.

assignment Homework

Matrix Elements and Completeness Relations

Completeness Relations

Quantum Fundamentals 2023 (3 years)

Writing an operator in matrix notation in its own basis is easy: it is diagonal with the eigenvalues on the diagonal.

What if I want to calculate the matrix elements using a different basis??

The eigenvalue equation tells me what happens when an operator acts on its own eigenstate. For example: \(\hat{S}_y\left|{\pm}\right\rangle _y=\pm\frac{\hbar}{2}\left|{\pm}\right\rangle _y\)

In Dirac bra-ket notation, to know what an operator does to a ket, I needs to write the ket in the basis that is the eigenstates of the operator (in order to use the eigenvalue equation.)

One way to do this to stick completeness relationships into the braket: \begin{eqnarray*} \left\langle {+}\right|\hat{S_y}\left|{+}\right\rangle = \left\langle {+}\right|(I)\hat{S_y}(I)\left|{+}\right\rangle \end{eqnarray*}

where \(I\) is the identity operator: \(I=\color{blue}{\left|{+}\right\rangle _{yy}\left\langle {+}\right|}\;+\;\color{blue}{\left|{-}\right\rangle _{yy}\left\langle {-}\right|}\). This effectively rewrite the \(\left|{+}\right\rangle \) in the \(\left|{\pm}\right\rangle _y\) basis.

Find the top row matrix elements of the operator \(\hat{S}_y\) in the \(S_z\) basis by inserting completeness relations into the brakets. (The answer is already on the Spins Reference Sheet, but I want you do demonstrate the calculation.)

assignment Homework

Completeness Relation Change of Basis
change of basis spin half completeness relation dirac notation

Completeness Relations

Quantum Fundamentals 2023 (3 years)
  1. Given the polar basis kets written as a superposition of Cartesian kets \begin{eqnarray*} \left|{\hat{s}}\right\rangle &=& \cos\phi \left|{\hat{x}}\right\rangle + \sin\phi \left|{\hat{y}}\right\rangle \\ \left|{\hat{\phi}}\right\rangle &=& -\sin\phi \left|{\hat{x}}\right\rangle + \cos\phi \left|{\hat{y}}\right\rangle \end{eqnarray*}

    Find the following quantities: \[\left\langle {\hat{x}}\middle|{\hat{s}}\right\rangle ,\quad \left\langle {\hat{y}}\middle|{{\hat{s}}}\right\rangle ,\quad \left\langle {\hat{x}}\middle|{\hat{\phi}}\right\rangle ,\quad \left\langle {\hat{y}}\middle|{\hat{\phi}}\right\rangle \]

  2. Given a vector written in the polar basis \[\left|{\vec{v}}\right\rangle = a\left|{\hat{s}}\right\rangle + b\left|{\hat{\phi}}\right\rangle \] where \(a\) and \(b\) are known. Find coefficients \(c\) and \(d\) such that \[\left|{\vec{v}}\right\rangle = c\left|{\hat{x}}\right\rangle + d\left|{\hat{y}}\right\rangle \] Do this by using the completeness relation: \[\left|{\hat{x}}\right\rangle \left\langle {\hat{x}}\right| + \left|{\hat{y}}\right\rangle \left\langle {\hat{y}}\right| = 1\]
  3. Using a completeness relation, change the basis of the spin-1/2 state \[\left|{\Psi}\right\rangle = g\left|{+}\right\rangle + h\left|{-}\right\rangle \] into the \(S_y\) basis. In otherwords, find \(j\) and \(k\) such that \[\left|{\Psi}\right\rangle = j\left|{+}\right\rangle _y + k\left|{-}\right\rangle _y\]

group Small Group Activity

30 min.

Expectation Values for a Particle on a Ring
Central Forces 2023 (3 years)

central forces quantum mechanics eigenstates eigenvalues hermitian operators quantum measurements degeneracy expectation values time dependence

Quantum Ring Sequence

Students calculate the expectation value of energy and angular momentum as a function of time for an initial state for a particle on a ring. This state is a linear combination of energy/angular momentum eigenstates written in bra-ket notation.

group Small Group Activity

30 min.

Time Evolution of a Spin-1/2 System
Quantum Fundamentals 2023 (3 years)

quantum mechanics spin precession time evolution

In this small group activity, students solve for the time dependence of two quantum spin 1/2 particles under the influence of a Hamiltonian. Students determine, given a Hamiltonian, which states are stationary and under what circumstances measurement probabilities do change with time.

group Small Group Activity

120 min.

Representations of the Infinite Square Well
Quantum Fundamentals 2023 (3 years)

Warm-Up

group Small Group Activity

30 min.

Outer Product of a Vector on Itself
Quantum Fundamentals 2023 (2 years)

Projection Operators Outer Products Matrices

Completeness Relations

Students compute the outer product of a vector on itself to product a projection operator. Students discover that projection operators are idempotent (square to themselves) and that a complete set of outer products of an orthonormal basis is the identity (a completeness relation).

assignment Homework

Frequency
Quantum Mechanics Time Evolution Spin Precession Expectation Value Bohr Frequency Quantum Fundamentals 2023 (3 years) Consider a two-state quantum system with a Hamiltonian \begin{equation} \hat{H}\doteq \begin{pmatrix} E_1&0\\ 0&E_2 \end{pmatrix} \end{equation} Another physical observable \(M\) is described by the operator \begin{equation} \hat{M}\doteq \begin{pmatrix} 0&c\\ c&0 \end{pmatrix} \end{equation} where \(c\) is real and positive. Let the initial state of the system be \(\left|{\psi(0)}\right\rangle =\left|{m_1}\right\rangle \), where \(\left|{m_1}\right\rangle \) is the eigenstate corresponding to the larger of the two possible eigenvalues of \(\hat{M}\). What is the frequency of oscillation of the expectation value of \(M\)? This frequency is the Bohr frequency.

face Lecture

5 min.

Unit Learning Outcomes: Quantum Mechanics on a Ring
Central Forces 2023

assignment Homework

Summation Notation, Version 0
Central Forces 2023 Write out the terms in the following sums that have the lowest energy. Stop when you have at least 9 terms, but only stop at some point that is logical, given the symmetries and degeneracies. Briefly explain why you chose to stop when you did. You may have to guess what system you are working from the form of the sum and which eigenvalue(s) determine the energy. You may assume that low energies correspond to eigenvalues near zero. Clearly state any assumptions that you make. You may use bra/ket notation in your solutions. (If these directions are unclear, check out the solutions below for some examples.)
  1. \[\sum_{m=-\infty}^{\infty} c_m e^{im\phi}\]
  2. \[\sum_{m=1}^{\infty}\sum_{n=1}^{\infty} c_{mn} \sin\left(\frac{m\pi x}{L_x}\right)\sin\left(\frac{n\pi y}{L_y}\right)\]
  3. \[\sum_{n=1}^{\infty}\sum_{\ell=0}^{n-1}\sum_{m=-\ell}^{\ell} c_{n \ell m} \left|{n, \ell, m}\right\rangle \]

group Small Group Activity

30 min.

Time Dependence for a Quantum Particle on a Ring Part 1
Theoretical Mechanics (6 years)

central forces quantum mechanics eigenstates eigenvalues angular momentum time dependence hermitian operators probability degeneracy quantum measurements

Quantum Ring Sequence

Students calculate probabilities for energy, angular momentum, and position as a function of time for an initial state that is a linear combination of energy/angular momentum eigenstates for a particle confined to a ring written in bra-ket notation. This activity helps students build an understanding of when they can expect a quantity to depend on time and to give them more practice moving between representations.

assignment Homework

Working with Representations on the Ring
Central Forces 2023 (3 years)

The following are 3 different representations for the \(\textbf{same}\) state on a quantum ring for \(r_0=1\) \begin{equation} \left|{\Phi_a}\right\rangle = i\sqrt{\frac{ 2}{12}}\left|{3}\right\rangle - \sqrt{\frac{ 1}{12}}\left|{1}\right\rangle +\sqrt{\frac{ 3}{12}}e^{i\frac{\pi}{4}}\left|{0}\right\rangle -i\sqrt{\frac{ 2}{ 12}}\left|{-1}\right\rangle +\sqrt{\frac{ 4}{12}}\left|{-3}\right\rangle \end{equation} \begin{equation} \left| \Phi_b\right\rangle \doteq \left( \begin{matrix} \vdots \\ i\sqrt{\frac{ 2}{12}}\\ 0 \\ -\sqrt{\frac{ 1}{12}} \\ \sqrt{\frac{ 3}{12}}e^{i\frac{\pi}{4}} \\ -i\sqrt{\frac{ 2}{12}}\\ 0 \\ \sqrt{\frac{4}{12} }\\ \vdots \end{matrix}\right) \begin{matrix} \leftarrow m=0 \end{matrix} \end{equation} \begin{equation} \Phi_c(\phi) \doteq \sqrt{\frac{1}{24 \pi}} \left( i\sqrt{2}e^{i 3 \phi} -e^{i\phi} +\sqrt{3}e^{i\frac{\pi}{4}} -i \sqrt{2} e^{-i\phi} + \sqrt{4}e^{-i 3 \phi} \right) \end{equation}

  1. With each representation of the state given above, explicitly calculate the probability that \(L_z=-1\hbar\). Then, calculate all other non-zero probabilities for values of \(L_z\) with a method/representation of your choice.
  2. Explain how you could be sure you calculated all of the non-zero probabilities.
  3. If you measured the \(z\)-component of angular momentum to be \(3\hbar\), what would the state of the particle be immediately after the measurement is made?
  4. With each representation of the state given above, explicitly calculate the probability that \(E=\frac{9}{2}\frac{\hbar^2}{I}\). Then, calculate all other non-zero probabilities for values of \(E\) with a method of your choice.
  5. If you measured the energy of the state to be \(\frac{9}{2}\frac{\hbar^2}{I}\), what would the state of the particle be immediately after the measurement is made?

group Small Group Activity

60 min.

Expectation Value and Uncertainty for the Difference of Dice
Quantum Fundamentals 2023 (3 years)