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Quantum Ring Sequence
Students calculate probabilities and expectation values for a quantum mechanical particle confined to a circular ring in bra/ket, matrix, and wave function representations and compare the different calculation methods. Several different graphical representations of the time dependence for both states with special symmetry and arbitrary states are explored in a Mathematica notebook. Compared to the analogous particle-in-a-box, this quantum system has a new feature---degenerate energy eigenstates.

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Completeness Relations
This set of activities explores completeness relations in quantum mechanics and how they eventually support understanding of wavefunctions and what it means to be in the position or momentum representatations.

face Lecture

5 min.

Unit Learning Outcomes: Quantum Mechanics on a Ring
Central Forces 2023

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Fourier Transforms and Wave Packets
This is a unit that introduces the Fourier transform and its properties and then applies the Fourier transform to free particle wave packets in non-relativistic quantum mechanics. The activities and homework are listed here. Appropriate text materials for mini-lectures can be found in the chapter Fourier Transforms and Wave Packets in the free online textbook The Geometry of Mathematical Methods.

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Arms Sequence for Complex Numbers and Quantum States
“Arms” is an engaging representation of complex numbers in which students use their left arms to geometrically represent numbers in the complex plane (an Argand diagram). The sequence starts with pure math activities in which students represent a single complex number (using prompts in both rectangular and exponential forms), demonstrate multiplication of complex numbers in exponential form, and act out a number of different linear transformation on pairs of complex numbers. Later activities, relevant to spin 1/2 systems in quantum mechanics, explore overall phases, relative phases, and time dependence. These activities can be combined and sequenced in many different ways; see the Instructor's Guide for the second activity for ideas about how to introduce the Arms representation the first time you use it.

assignment_ind Small White Board Question

5 min.

Angular Momentum
Central Forces 2023

group Small Group Activity

30 min.

Expectation Values for a Particle on a Ring
Central Forces 2023 (3 years)

central forces quantum mechanics eigenstates eigenvalues hermitian operators quantum measurements degeneracy expectation values time dependence

Quantum Ring Sequence

Students calculate the expectation value of energy and angular momentum as a function of time for an initial state for a particle on a ring. This state is a linear combination of energy/angular momentum eigenstates written in bra-ket notation.

face Lecture

5 min.

Central Forces Introduction Lecture Notes
Central Forces 2022

assignment_ind Small White Board Question

5 min.

Normalization of the Gaussian for Wavefunctions
Periodic Systems 2022

Fourier Transforms and Wave Packets

Students find a wavefunction that corresponds to a Gaussian probability density.

group Small Group Activity

30 min.

Superposition States for a Particle on a Ring

central forces quantum mechanics eigenstates eigenvalues quantum measurements angular momentum hermitian operators probability superposition

Quantum Ring Sequence

Students calculate probabilities for a particle on a ring whose wavefunction is not easily separated into eigenstates by inspection. To find the energy, angular momentum, and position probabilities, students perform integrations with the wavefunction or decompose the wavefunction into a superposition of eigenfunctions.

assignment Homework

Quantum concentration
bose-einstein gas statistical mechanics Thermal and Statistical Physics 2020 Consider one particle confined to a cube of side \(L\); the concentration in effect is \(n=L^{-3}\). Find the kinetic energy of the particle when in the ground state. There will be a value of the concentration for which this zero-point quantum kinetic energy is equal to the temperature \(kT\). (At this concentration the occupancy of the lowest orbital is of the order of unity; the lowest orbital always has a higher occupancy than any other orbital.) Show that the concentration \(n_0\) thus defined is equal to the quantum concentration \(n_Q\) defined by (63): \begin{equation} n_Q \equiv \left(\frac{MkT}{2\pi\hbar^2}\right)^{\frac32} \end{equation} within a factor of the order of unity.

group Small Group Activity

30 min.

Energy and Angular Momentum for a Quantum Particle on a Ring

central forces quantum mechanics eigenstates eigenvalues quantum measurements angular momentum energy hermitian operators probability superposition representations notations degeneracy

Quantum Ring Sequence

Students calculate probabilities for a particle on a ring using three different notations: Dirac bra-ket, matrix, and wave function. After calculating the angular momentum and energy measurement probabilities, students compare their calculation methods for notation.

assignment Homework

Distribution function for double occupancy statistics
Orbitals Distribution function Thermal and Statistical Physics 2020

Let us imagine a new mechanics in which the allowed occupancies of an orbital are 0, 1, and 2. The values of the energy associated with these occupancies are assumed to be \(0\), \(\varepsilon\), and \(2\varepsilon\), respectively.

  1. Derive an expression for the ensemble average occupancy \(\langle N\rangle\), when the system composed of this orbital is in thermal and diffusive contact with a resevoir at temperature \(T\) and chemical potential \(\mu\).

  2. Return now to the usual quantum mechanics, and derive an expression for the ensemble average occupancy of an energy level which is doubly degenerate; that is, two orbitals have the identical energy \(\varepsilon\). If both orbitals are occupied the toal energy is \(2\varepsilon\). How does this differ from part (a)?

group Small Group Activity

5 min.

Fourier Transform of the Delta Function
Periodic Systems 2022

Fourier Transforms and Wave Packets

Students calculate the Fourier transform of the Dirac delta function.

computer Mathematica Activity

30 min.

Visualization of Quantum Probabilities for the Hydrogen Atom
Central Forces 2023 (3 years) Students use Mathematica to visualize the probability density distribution for the hydrogen atom orbitals with the option to vary the values of \(n\), \(\ell\), and \(m\).

group Small Group Activity

30 min.

Time Evolution of a Spin-1/2 System
Quantum Fundamentals 2023 (3 years)

quantum mechanics spin precession time evolution

In this small group activity, students solve for the time dependence of two quantum spin 1/2 particles under the influence of a Hamiltonian. Students determine, given a Hamiltonian, which states are stationary and under what circumstances measurement probabilities do change with time.

group Small Group Activity

60 min.

Going from Spin States to Wavefunctions
Quantum Fundamentals 2023 (2 years)

Wavefunctions quantum states probability amplitude histograms matrix notation of quantum states Arms representation

Arms Sequence for Complex Numbers and Quantum States

Completeness Relations

Students review using the Arms representation to represent states for discrete quantum systems and connecting the Arms representation to histogram and matrix representation. The student then extend the Arms representation to begin exploring the continuous position basis.

assignment Homework

Phase
Complex Numbers Rectangular Form Exponential Form Square of the Norm Overall Phase Quantum Fundamentals 2023 (3 years)
  1. For each of the following complex numbers \(z\), find \(z^2\), \(\vert z\vert^2\), and rewrite \(z\) in exponential form, i.e. as a magnitude times a complex exponential phase:

    • \(z_1=i\),

    • \(z_2=2+2i\),
    • \(z_3=3-4i\).
  2. In quantum mechanics, it turns out that the overall phase for a state does not have any physical significance. Therefore, you will need to become quick at rearranging the phase of various states. For each of the vectors listed below, rewrite the vector as an overall complex phase times a new vector whose first component is real and positive. \[\left|D\right\rangle\doteq \begin{pmatrix} 7e^{i\frac{\pi}{6}}\\ 3e^{i\frac{\pi}{2}}\\ -1\\ \end{pmatrix}\\ \left|E\right\rangle\doteq \begin{pmatrix} i\\ 4\\ \end{pmatrix}\\ \left|F\right\rangle\doteq \begin{pmatrix} 2+2i\\ 3-4i\\ \end{pmatrix} \]

assignment Homework

Frequency
Quantum Mechanics Time Evolution Spin Precession Expectation Value Bohr Frequency Quantum Fundamentals 2023 (3 years) Consider a two-state quantum system with a Hamiltonian \begin{equation} \hat{H}\doteq \begin{pmatrix} E_1&0\\ 0&E_2 \end{pmatrix} \end{equation} Another physical observable \(M\) is described by the operator \begin{equation} \hat{M}\doteq \begin{pmatrix} 0&c\\ c&0 \end{pmatrix} \end{equation} where \(c\) is real and positive. Let the initial state of the system be \(\left|{\psi(0)}\right\rangle =\left|{m_1}\right\rangle \), where \(\left|{m_1}\right\rangle \) is the eigenstate corresponding to the larger of the two possible eigenvalues of \(\hat{M}\). What is the frequency of oscillation of the expectation value of \(M\)? This frequency is the Bohr frequency.

assignment Homework

Fourier Transform of Cosine and Sine
Periodic Systems 2022
  1. Find the Fourier transforms of \(f(x)=\cos kx\) and \(g(x)=\sin kx\).
  2. Find the Fourier transform of \(g(x)\) using the formula for the Fourier transform of a derivative and your result for the Fourier transform of \(f(x)\). Compare with your previous answer.
  3. In quantum mechanics, the Fourier transform is the set of coefficients in the expansion of a quantum state in terms of plane waves, i.e. the function \(\tilde{f}(k)\) is a continuous histogram of how much each functions \(e^{ikx}\) contributes to the quantum state. What does the Fourier transform of the function \(\cos kx\) tell you about which plane waves make up this quantum state? Write a sentence or two about how this makes sense.