Activities
Students will determine the change in entropy (positive, negative, or none) for both the system and surroundings in three different cases. This is followed by an active whole-class discussion about where the entropy comes from during an irreversible process.
Problem
A diesel engine requires no spark plug. Rather, the air in the cylinder is compressed so highly that the fuel ignites spontaneously when sprayed into the cylinder.
In this problem, you may treat air as an ideal gas, which satisfies the equation \(pV = Nk_BT\). You may also use the property of an ideal gas that the internal energy depends only on the temperature \(T\), i.e. the internal energy does not change for an isothermal process. For air at the relevant range of temperatures the heat capacity at fixed volume is given by \(C_V=\frac52Nk_B\), which means the internal energy is given by \(U=\frac52Nk_BT\).
Note: in this problem you are expected to use only the equations given and fundamental physics laws. Looking up the formula in a textbook is not considered a solution at this level.
If the air is initially at room temperature (taken as \(20^{o}C\)) and is then compressed adiabatically to \(\frac1{15}\) of the original volume, what final temperature is attained (before fuel injection)?
- By what factor does the pressure increase?
The isothermal compressibility is defined as \begin{equation} K_{T}=-\frac{1}{V} \left(\frac{\partial V}{\partial p}\right)_{T} \end{equation} \(K_T\) is be found by measuring the fractional change in volume when the the pressure is slightly changed with the temperature held constant. In contrast, the adiabatic compressibility is defined as \begin{equation} K_{S}=-\frac{1}{V} \left(\frac{\partial V}{\partial p}\right)_{S} \end{equation} and is measured by making a slight change in pressure without allowing for any heat transfer. This is the compressibility, for instance, that would directly affect the speed of sound. Show that \begin{equation} \frac{K_{T}}{K_{S}} = \frac{C_{p}}{C_{V}} \end{equation} Where the heat capacities at constant pressure and volume are given by \begin{align} C_{p} &= T \left(\frac{\partial S}{\partial T}\right)_{p} \\ C_{V} &= T \left(\frac{\partial S}{\partial T}\right)_{V} \end{align}
Problem
The internal energy is of any ideal gas can be written as \begin{align} U &= U(T,N) \end{align} meaning that the internal energy depends only on the number of particles and the temperature, but not the volume.^{*}
The ideal gas law \begin{align} pV &= Nk_BT \end{align} defines the relationship between \(p\), \(V\) and \(T\). You may take the number of molecules \(N\) to be constant. Consider the free adiabatic expansion of an ideal gas to twice its volume. “Free expansion” means that no work is done, but also that the process is also neither quasistatic nor reversible.
What is the change in entropy of the gas? How do you know this?
- What is the change in temperature of the gas?
Students use prepared Sage code or a prepared Mathematica notebook to plot \(\sin\theta\) simultaneously with several terms of a power series expansion to judge how well the approximation fits. Students can alter the worksheet to change the number of terms in the expansion and even to change the function that is being considered. Students should have already calculated the coefficients for the power series expansion in a previous activity, Calculating Coefficients for a Power Series.
Students work in small groups to use the superposition principle \[\vec{A}(\vec{r}) =\frac{\mu_0}{4\pi}\int\frac{\vec{J}(\vec{r}^{\,\prime})}{\vert \vec{r}-\vec{r}^{\,\prime}\vert}\, d\tau^{\prime}\] to find an integral expression for the magnetic vector potential, \(\vec{A}(\vec{r})\), due to a spinning ring of charge.
In an optional extension, students find a series expansion for \(\vec{A}(\vec{r})\) either on the axis or in the plane of the ring, for either small or large values of the relevant geometric variable. Add an extra half hour or more to the time estimate for the optional extension.
Students work in small groups to use the Biot-Savart law \[\vec{B}(\vec{r}) =\frac{\mu_0}{4\pi}\int\frac{\vec{J}(\vec{r}^{\,\prime})\times \left(\vec{r}-\vec{r}^{\,\prime}\right)}{\vert \vec{r}-\vec{r}^{\,\prime}\vert^3} \, d\tau^{\prime}\] to find an integral expression for the magnetic field, \(\vec{B}(\vec{r})\), due to a spinning ring of charge.
In an optional extension, students find a series expansion for \(\vec{B}(\vec{r})\) either on the axis or in the plane of the ring, for either small or large values of the relevant geometric variable. Add an extra half hour or more to the time estimate for the optional extension.
Students work in small groups to use Coulomb's Law \[\vec{E}(\vec{r}) =\frac{1}{4\pi\epsilon_0}\int\frac{\rho(\vec{r}^{\,\prime})\left(\vec{r}-\vec{r}^{\,\prime}\right)}{\vert \vec{r}-\vec{r}^{\,\prime}\vert^3} \, d\tau^{\prime}\] to find an integral expression for the electric field, \(\vec{E}(\vec{r})\), everywhere in space, due to a ring of charge.
In an optional extension, students find a series expansion for \(\vec{E}(\vec{r})\) either on the axis or in the plane of the ring, for either small or large values of the relevant geometric variable. Add an extra half hour or more to the time estimate for the optional extension.
Students work in small groups to use the superposition principle \[V(\vec{r}) = \frac{1}{4\pi\epsilon_0}\sum_i \frac{q_i}{\vert\vec{r}-\vec{r}_i\vert}\] to find the electrostatic potential \(V\) everywhere in space due to a pair of charges (either identical charges or a dipole). Different groups are assigned different arrangements of charges and different regions of space to consider: either on the axis of the charges or in the plane equidistant from the two charges, for either small or large values of the relevant geometric variable. Each group is asked to find a power series expansion for the electrostatic potential, valid in their group's assigned region of space. The whole class wrap-up discussion then compares and contrasts the results and discuss the symmetries of the two cases.
Students work in small groups to use the superposition principle \[V(\vec{r}) =\frac{1}{4\pi\epsilon_0}\int\frac{\rho(\vec{r}^{\,\prime})}{\vert \vec{r}-\vec{r}^{\,\prime}\vert} \, d\tau^{\prime}\] to find an integral expression for the electrostatic potential, \(V(\vec{r})\), everywhere in space, due to a ring of charge.
In an optional extension, students find a series expansion for \(V(\vec{r})\) either on the axis or in the plane of the ring, for either small or large values of the relevant geometric variable. Add an extra half hour or more to the time estimate for the optional extension.