Activities
Students calculate two different (thermodynamic) partial derivatives of the form \(\left(\frac{\partial A}{\partial B}\right)_C\) from information given on the same contour map.
This small group activity using surfaces introduces a geometric interpretation of partial derivatives in terms of measured ratios of small changes. Students work in small groups to identify locations on their surface with particular properties. The whole class wrap-up discussion emphasizes the equivalence of multiple representations of partial derivatives.
Student groups design an experiment that measures an assigned partial derivative. In a compare-and-contrast wrap-up, groups report on how they would measure their derivatives.
In this introduction to heat capacity, students determine a derivative that indicates how much the internal energy changes as the temperature changes when volume is held constant.
In this sequence of small whiteboard questions, students are shown the contour graph of a function of two variables and asked to find the derivative. They discover that, without a function to differentiate, they must instead think of the derivative as a ratio of small changes. This requires them to pick two nearby points. Which two?
This mini-lecture demonstrates the relationship between \(df\) on the tangent plane to its “components“ in coordinate directions, leading to the multivariable chain rule.
This small group activity using surfaces relates the geometric definition of directional derivatives to the components of the gradient vector. Students work in small groups to measure a directional derivative directly, then compare its components with measured partial derivatives in rectangular coordinates. The whole class wrap-up discussion emphasizes the relationship between the geometric gradient vector and directional derivatives.
In this activity, students will explore how to calculate a derivative from measured data. Students should have prior exposure to differential calculus. At the start of the activity, orient the students to the contour plot - it's busy.
Students examine a plastic "surface" graph of the gravitational potential energy of a Earth-satellite system to make connections between gravitational force and gravitational potential energy.
Write one thing you know about the derivative.
Problem
Use the NIST web site “Thermophysical Properties of Fluid Systems” to answer the following questions. This site is an excellent resource for finding experimentally measured properties of fluids.
- Find the partial derivatives \[\left(\frac{\partial {S}}{\partial {T}}\right)_{p}\] \[\left(\frac{\partial {S}}{\partial {T}}\right)_{V}\] where \(p\) is the pressure, \(V\) is the volume, \(S\) is the entropy, and \(T\) is the temperature. Please find these derivatives for one gram of methanol at one atmosphere of pressure and at room temperature.
- Why does it take only two variables to define the state?
- Why are the derivatives above different?
- What do the words isobaric, isothermal, and isochoric mean?
This small group activity using surfaces combines practice with the multivariable chain rule while emphasizing numerical representations of derivatives. Students work in small groups to measure partial derivatives in both rectangular and polar coordinates, then verify their results using the chain rule. The whole class wrap-up discussion emphasizes the relationship between a directional derivative in the \(r\)-direction and derivatives in \(x\)- and \(y\)-directions using the chain rule.
- Students evaluate two given partial derivatives from a system of equations.
- Students learn/review generalized Leibniz notation.
- Students may find it helpful to use a chain rule diagram.
This short small group activity introduces students to the Leibniz notation used for partial derivatives in thermodynamics, in which the variables being held constant are given explicitly. Students are guided to associate variables to their proper categories.
This small group activity is designed to provide practice with the chain rule and to develop familiarity with polar coordinates. Students work in small groups to relate partial derivatives in rectangular and polar coordinates. The whole class wrap-up discussion emphasizes the importance of specifying what quantities are being held constant.
Students are placed into small groups and asked to create an experimental setup they can use to measure the partial derivative they are given, in which entropy changes.