## Extensive Internal Energy

• assignment Mass Density

assignment Homework

##### Mass Density
Static Fields 2023 (4 years) Consider a rod of length $L$ lying on the $z$-axis. Find an algebraic expression for the mass density of the rod if the mass density at $z=0$ is $\lambda_0$ and at $z=L$ is $7\lambda_0$ and you know that the mass density increases
• linearly;
• like the square of the distance along the rod;
• exponentially.
• group Proportional Reasoning

group Small Group Activity

10 min.

##### Proportional Reasoning
Static Fields 2023 (3 years) In this small group activity, students calculate a (linear) function to represent the charge density on a one-dimensional rod from a description of the charge density in words.
• assignment Charge on a Spiral

assignment Homework

##### Charge on a Spiral
Static Fields 2023 (2 years) A charged spiral in the $x,y$-plane has 6 turns from the origin out to a maximum radius $R$ , with $\phi$ increasing proportionally to the distance from the center of the spiral. Charge is distributed on the spiral so that the charge density increases linearly as the radial distance from the center increases. At the center of the spiral the linear charge density is $0~\frac{\textrm{C}}{\textrm{m}}$. At the end of the spiral, the linear charge density is $13~\frac{\textrm{C}}{\textrm{m}}$. What is the total charge on the spiral?
• assignment Helix

assignment Homework

##### Helix

Integration Sequence

Static Fields 2023 (6 years)

A helix with 17 turns has height $H$ and radius $R$. Charge is distributed on the helix so that the charge density increases like (i.e. proportional to) the square of the distance up the helix. At the bottom of the helix the linear charge density is $0~\frac{\textrm{C}}{\textrm{m}}$. At the top of the helix, the linear charge density is $13~\frac{\textrm{C}}{\textrm{m}}$. What is the total charge on the helix?

• assignment Gibbs sum for a two level system

assignment Homework

##### Gibbs sum for a two level system
Gibbs sum Microstate Thermal average energy Thermal and Statistical Physics 2020
1. Consider a system that may be unoccupied with energy zero, or occupied by one particle in either of two states, one of energy zero and one of energy $\varepsilon$. Find the Gibbs sum for this system is in terms of the activity $\lambda\equiv e^{\beta\mu}$. Note that the system can hold a maximum of one particle.

2. Solve for the thermal average occupancy of the system in terms of $\lambda$.

3. Show that the thermal average occupancy of the state at energy $\varepsilon$ is \begin{align} \langle N(\varepsilon)\rangle = \frac{\lambda e^{-\frac{\varepsilon}{kT}}}{\mathcal{Z}} \end{align}

4. Find an expression for the thermal average energy of the system.

5. Allow the possibility that the orbitals at $0$ and at $\varepsilon$ may each be occupied each by one particle at the same time; Show that \begin{align} \mathcal{Z} &= 1 + \lambda + \lambda e^{-\frac{\varepsilon}{kT}} + \lambda^2 e^{-\frac{\varepsilon}{kT}} \\ &= (1+\lambda)\left(1+e^{-\frac{\varepsilon}{kT}}\right) \end{align} Because $\mathcal{Z}$ can be factored as shown, we have in effect two independent systems.

• assignment Cube Charge

assignment Homework

##### Cube Charge
charge density

Integration Sequence

Static Fields 2023 (6 years)
1. Charge is distributed throughout the volume of a dielectric cube with charge density $\rho=\beta z^2$, where $z$ is the height from the bottom of the cube, and where each side of the cube has length $L$. What is the total charge inside the cube? Do this problem in two ways as both a single integral and as a triple integral.
2. On a different cube: Charge is distributed on the surface of a cube with charge density $\sigma=\alpha z$ where $z$ is the height from the bottom of the cube, and where each side of the cube has length $L$. What is the total charge on the cube? Don't forget about the top and bottom of the cube.
• face Gibbs entropy approach

face Lecture

120 min.

##### Gibbs entropy approach
Thermal and Statistical Physics 2020

These lecture notes for the first week of Thermal and Statistical Physics include a couple of small group activities in which students work with the Gibbs formulation of the entropy.
• group Total Charge

group Small Group Activity

30 min.

##### Total Charge
Static Fields 2023 (6 years)

Integration Sequence

In this small group activity, students integrate over non-uniform charge densities in cylindrical and spherical coordinates to calculate total charge.
• assignment Carbon monoxide poisoning

assignment Homework

##### Carbon monoxide poisoning
Equilibrium Absorbtion Thermal and Statistical Physics 2020

In carbon monoxide poisoning the CO replaces the $\textsf{O}_{2}$ adsorbed on hemoglobin ($\text{Hb}$) molecules in the blood. To show the effect, consider a model for which each adsorption site on a heme may be vacant or may be occupied either with energy $\varepsilon_A$ by one molecule $\textsf{O}_{2}$ or with energy $\varepsilon_B$ by one molecule CO. Let $N$ fixed heme sites be in equilibrium with $\textsf{O}_{2}$ and CO in the gas phases at concentrations such that the activities are $\lambda(\text{O}_2) = 1\times 10^{-5}$ and $\lambda(\text{CO}) = 1\times 10^{-7}$, all at body temperature $37^\circ\text{C}$. Neglect any spin multiplicity factors.

1. First consider the system in the absence of CO. Evaluate $\varepsilon_A$ such that 90 percent of the $\text{Hb}$ sites are occupied by $\textsf{O}_{2}$. Express the answer in eV per $\textsf{O}_{2}$.

2. Now admit the CO under the specified conditions. Fine $\varepsilon_B$ such that only 10% of the Hb sites are occupied by $\textsf{O}_{2}$.

• assignment Electric Field from a Rod

assignment Homework

##### Electric Field from a Rod
Static Fields 2023 (5 years) Consider a thin charged rod of length $L$ standing along the $z$-axis with the bottom end on the $xy$-plane. The charge density $\lambda$ is constant. Find the electric field at the point $(0,0,2L)$.
• Energy and Entropy 2021 (2 years)

Consider a system which has an internal energy $U$ defined by: \begin{align} U &= \gamma V^\alpha S^\beta \end{align} where $\alpha$, $\beta$ and $\gamma$ are constants. The internal energy is an extensive quantity. What constraint does this place on the values $\alpha$ and $\beta$ may have?