assignment Homework
Suppose that a system of \(N\) atoms of type \(A\) is placed in diffusive contact with a system of \(N\) atoms of type \(B\) at the same temperature and volume.
Show that after diffusive equilibrium is reached the total entropy is increased by \(2Nk\ln 2\). The entropy increase \(2Nk\ln 2\) is known as the entropy of mixing.
If the atoms are identical (\(A=B\)), show that there is no increase in entropy when diffusive contact is established. The difference has been called the Gibbs paradox.
Since the Helmholtz free energy is lower for the mixed \(AB\) than for the separated \(A\) and \(B\), it should be possible to extract work from the mixing process. Construct a process that could extract work as the two gasses are mixed at fixed temperature. You will probably need to use walls that are permeable to one gas but not the other.
This course has not yet covered work, but it was covered in Energy and Entropy, so you may need to stretch your memory to finish part (c).
assignment Homework
assignment Homework
Consider a collection of three charges arranged in a line along the \(z\)-axis: charges \(+Q\) at \(z=\pm D\) and charge \(-2Q\) at \(z=0\).
face Lecture
120 min.
paramagnet entropy temperature statistical mechanics
These lecture notes for the second week of Thermal and Statistical Physics involve relating entropy and temperature in the microcanonical ensemble, using a paramagnet as an example. These notes include a few small group activities.assignment Homework
Find the electrostatic potential at a point \(\vec{r}\) on the \(x\)-axis at a distance \(x\) from the center of the quadrupole.
A series of charges arranged in this way is called a linear quadrupole. Why?
assignment Homework
Consider the finite line with a uniform charge density from class.
assignment Homework
For an infinitesimally thin cylindrical shell of radius \(b\) with uniform surface charge density \(\sigma\), the electric field is zero for \(s<b\) and \(\vec{E}= \frac{\sigma b}{\epsilon_0 s}\, \hat s\) for \(s > b\). Use the differential form of Gauss' Law to find the charge density everywhere in space.
assignment Homework
Consider the fields at a point \(\vec{r}\) due to a point charge located at \(\vec{r}'\).
assignment Homework
In this course, two of the primary examples we will be using are the potential due to gravity and the potential due to an electric charge. Both of these forces vary like \(\frac{1}{r}\), so they will have many, many similarities. Most of the calculations we do for the one case will be true for the other. But there are some extremely important differences:
assignment Homework
The electrostatic potential due to a point charge at the origin is given by: \begin{equation} V=\frac{1}{4\pi\epsilon_0} \frac{q}{r} \end{equation}
Find the electric field around an infinite, uniformly charged, straight wire, starting from the following expression for the electrostatic potential: \begin{equation} V(\vec r)=\frac{2\lambda}{4\pi\epsilon_0}\, \ln\left( \frac{ s_0}{s} \right) \end{equation}