## Isolength and Isoforce Stretchability

• assignment Paramagnet (multiple solutions)

assignment Homework

##### Paramagnet (multiple solutions)
Energy and Entropy 2021 (2 years) We have the following equations of state for the total magnetization $M$, and the entropy $S$ of a paramagnetic system: \begin{align} M&=N\mu\, \frac{e^{\frac{\mu B}{k_B T}} - e^{-\frac{\mu B}{k_B T}}} {e^{\frac{\mu B}{k_B T}} + e^{-\frac{\mu B}{k_B T}}}\\ S&=Nk_B\left\{\ln 2 + \ln \left(e^{\frac{\mu B}{k_B T}}+e^{-\frac{\mu B}{k_B T}}\right) +\frac{\mu B}{k_B T} \frac{e^{\frac{\mu B}{k_B T}} - e^{-\frac{\mu B}{k_B T}}} {e^{\frac{\mu B}{k_B T}} + e^{-\frac{\mu B}{k_B T}}} \right\} \end{align}
1. List variables in their proper positions in the middle columns of the charts below.

2. Solve for the magnetic susceptibility, which is defined as: $\chi_B=\left(\frac{\partial M}{\partial B}\right)_T$

3. Using both the differentials (zapping with d) and chain rule diagram methods, find a chain rule for:

$\left(\frac{\partial M}{\partial B}\right)_S$

4. Evaluate your chain rule. Sense-making: Why does this come out to zero?

• group Paramagnet (multiple solutions)

group Small Group Activity

30 min.

##### Paramagnet (multiple solutions)
• Students evaluate two given partial derivatives from a system of equations.
• Students learn/review generalized Leibniz notation.
• Students may find it helpful to use a chain rule diagram.

assignment Homework

Energy and Entropy 2021 (2 years)

The isothermal compressibility is defined as $$K_{T}=-\frac{1}{V} \left(\frac{\partial V}{\partial p}\right)_{T}$$ $K_T$ is be found by measuring the fractional change in volume when the the pressure is slightly changed with the temperature held constant. In contrast, the adiabatic compressibility is defined as $$K_{S}=-\frac{1}{V} \left(\frac{\partial V}{\partial p}\right)_{S}$$ and is measured by making a slight change in pressure without allowing for any heat transfer. This is the compressibility, for instance, that would directly affect the speed of sound. Show that $$\frac{K_{T}}{K_{S}} = \frac{C_{p}}{C_{V}}$$ Where the heat capacities at constant pressure and volume are given by \begin{align} C_{p} &= T \left(\frac{\partial S}{\partial T}\right)_{p} \\ C_{V} &= T \left(\frac{\partial S}{\partial T}\right)_{V} \end{align}

• assignment Rubber Sheet

assignment Homework

##### Rubber Sheet
Energy and Entropy 2021 (2 years)

Consider a hanging rectangular rubber sheet. We will consider there to be two ways to get energy into or out of this sheet: you can either stretch it vertically or horizontally. The distance of vertical stretch we will call $y$, and the distance of horizontal stretch we will call $x$.

If I pull the bottom down by a small distance $\Delta y$, with no horizontal force, what is the resulting change in width $\Delta x$? Express your answer in terms of partial derivatives of the potential energy $U(x,y)$.

• face Energy and heat and entropy

face Lecture

30 min.

##### Energy and heat and entropy
Energy and Entropy 2021 (2 years)

This short lecture introduces the ideas required for Ice Calorimetry Lab or Microwave oven Ice Calorimetry Lab.
• face Energy and Entropy review

face Lecture

5 min.

##### Energy and Entropy review
Thermal and Statistical Physics 2020 (3 years)

This very quick lecture reviews the content taught in Energy and Entropy, and is the first content in Thermal and Statistical Physics.
• face Phase transformations

face Lecture

120 min.

##### Phase transformations
Thermal and Statistical Physics 2020

These lecture notes from the ninth week of Thermal and Statistical Physics cover phase transformations, the Clausius-Clapeyron relation, mean field theory and more. They include a number of small group activities.
• group Generalized Leibniz Notation

group Small Group Activity

10 min.

##### Generalized Leibniz Notation
Static Fields 2023 (5 years) This short small group activity introduces students to the Leibniz notation used for partial derivatives in thermodynamics; unlike standard Leibniz notation, this notation explicitly specifies constant variables. Students are guided in linking the variables from a contextless Leibniz-notation partial derivative to their proper variable categories.
• assignment Gibbs free energy

assignment Homework

##### Gibbs free energy
thermodynamics Maxwell relation Energy and Entropy 2020 The Gibbs free energy, $G$, is given by \begin{align*} G = U + pV - TS. \end{align*}
1. Find the total differential of $G$. As always, show your work.
2. Interpret the coefficients of the total differential $dG$ in order to find a derivative expression for the entropy $S$.
3. From the total differential $dG$, obtain a different thermodynamic derivative that is equal to $\left(\frac{\partial {S}}{\partial {p}}\right)_{T}$
• group Static Fields Equation Sheet

group Small Group Activity

5 min.

##### Static Fields Equation Sheet
Static Fields 2023 (5 years)
• Energy and Entropy 2021 (2 years)

In class, you measured the isolength stretchability and the isoforce stretchability of your systems in the PDM. We found that for some systems these were very different, while for others they were identical.

Show with algebra (NOT experiment) that the ratio of isolength stretchability to isoforce stretchability is the same for both the left-hand side of the system and the right-hand side of the system. i.e.: \begin{align} \frac{\left(\frac{\partial {x_L}}{\partial {F_L}}\right)_{x_R}}{\left(\frac{\partial {x_L}}{\partial {F_L}}\right)_{F_R}} &= \frac{\left(\frac{\partial {x_R}}{\partial {F_R}}\right)_{x_L}}{\left(\frac{\partial {x_R}}{\partial {F_R}}\right)_{F_L}} \label{eq:ratios} \end{align}

##### Hint
You will need to make use of the cyclic chain rule: \begin{align} \left(\frac{\partial {A}}{\partial {B}}\right)_{C} = -\left(\frac{\partial {A}}{\partial {C}}\right)_{B}\left(\frac{\partial {C}}{\partial {B}}\right)_{A} \end{align}
##### Hint
You will also need the ordinary chain rule: \begin{align} \left(\frac{\partial {A}}{\partial {B}}\right)_{D} = \left(\frac{\partial {A}}{\partial {C}}\right)_{D}\left(\frac{\partial {C}}{\partial {B}}\right)_{D} \end{align}