Quantum concentration

  • bose-einstein gas statistical mechanics
  • Thermal and Statistical Physics 2020 Consider one particle confined to a cube of side \(L\); the concentration in effect is \(n=L^{-3}\). Find the kinetic energy of the particle when in the ground state. There will be a value of the concentration for which this zero-point quantum kinetic energy is equal to the temperature \(kT\). (At this concentration the occupancy of the lowest orbital is of the order of unity; the lowest orbital always has a higher occupancy than any other orbital.) Show that the concentration \(n_0\) thus defined is equal to the quantum concentration \(n_Q\) defined by (63): \begin{equation} n_Q \equiv \left(\frac{MkT}{2\pi\hbar^2}\right)^{\frac32} \end{equation} within a factor of the order of unity.