assignment Homework

Ideal gas calculations
Ideal gas Entropy Sackur-Tetrode Thermal and Statistical Physics 2020

Consider one mole of an ideal monatomic gas at 300K and 1 atm. First, let the gas expand isothermally and reversibly to twice the initial volume; second, let this be followed by an isentropic expansion from twice to four times the original volume.

  1. How much heat (in joules) is added to the gas in each of these two processes?

  2. What is the temperature at the end of the second process?

  3. Suppose the first process is replaced by an irreversible expansion into a vacuum, to a total volume twice the initial volume. What is the increase of entropy in the irreversible expansion, in J/K?

assignment Homework

Entropy of mixing
Entropy Equilibrium Sackur-Tetrode Thermal and Statistical Physics 2020

Suppose that a system of \(N\) atoms of type \(A\) is placed in diffusive contact with a system of \(N\) atoms of type \(B\) at the same temperature and volume.

  1. Show that after diffusive equilibrium is reached the total entropy is increased by \(2Nk\ln 2\). The entropy increase \(2Nk\ln 2\) is known as the entropy of mixing.

  2. If the atoms are identical (\(A=B\)), show that there is no increase in entropy when diffusive contact is established. The difference has been called the Gibbs paradox.

  3. Since the Helmholtz free energy is lower for the mixed \(AB\) than for the separated \(A\) and \(B\), it should be possible to extract work from the mixing process. Construct a process that could extract work as the two gasses are mixed at fixed temperature. You will probably need to use walls that are permeable to one gas but not the other.

Note

This course has not yet covered work, but it was covered in Energy and Entropy, so you may need to stretch your memory to finish part (c).

face Lecture

120 min.

Work, Heat, and cycles
Thermal and Statistical Physics 2020

work heat engines Carnot thermodynamics entropy

These lecture notes covering week 8 of Thermal and Statistical Physics include a small group activity in which students derive the Carnot efficiency.

assignment Homework

Ideal gas in two dimensions
Ideal gas Entropy Chemical potential Thermal and Statistical Physics 2020
  1. Find the chemical potential of an ideal monatomic gas in two dimensions, with \(N\) atoms confined to a square of area \(A=L^2\). The spin is zero.

  2. Find an expression for the energy \(U\) of the gas.

  3. Find an expression for the entropy \(\sigma\). The temperature is \(kT\).

face Lecture

120 min.

Ideal Gas
Thermal and Statistical Physics 2020

ideal gas particle in a box grand canonical ensemble chemical potential statistical mechanics

These notes from week 6 of Thermal and Statistical Physics cover the ideal gas from a grand canonical standpoint starting with the solutions to a particle in a three-dimensional box. They include a number of small group activities.

face Lecture

120 min.

Boltzmann probabilities and Helmholtz
Thermal and Statistical Physics 2020

ideal gas entropy canonical ensemble Boltzmann probability Helmholtz free energy statistical mechanics

These notes, from the third week of Thermal and Statistical Physics cover the canonical ensemble and Helmholtz free energy. They include a number of small group activities.