assignment Homework

Quantum Particle in a 2-D Box
Central Forces 2023 (3 years) You know that the normalized spatial eigenfunctions for a particle in a 1-D box of length \(L\) are \(\sqrt{\frac{2}{L}}\sin{\frac{n\pi x}{L}}\). If you want the eigenfunctions for a particle in a 2-D box, then you just multiply together the eigenfunctions for a 1-D box in each direction. (This is what the separation of variables procedure tells you to do.)
  1. Find the normalized eigenfunctions for a particle in a 2-D box with sides of length \(L_x\) in the \(x\)-direction and length \(L_y\) in the \(y\)-direction.
  2. Find the Hamiltonian for a 2-D box and show that your eigenstates are indeed eigenstates and find a formula for the possible energies
  3. Any sufficiently smooth spatial wave function inside a 2-D box can be expanded in a double sum of the product wave functions, i.e. \begin{equation} \psi(x,y)=\sum_{n=1}^{\infty}\sum_{m=1}^{\infty}\, c_{nm}\; \hbox{eigenfunction}_n(x)\;\hbox{eigenfunction}_m(y) \end{equation} Using your expressions from part (a) above, write out all the terms in this sum out to \(n=3\), \(m=3\). Arrange the terms, conventionally, in terms of increasing energy.

    You may find it easier to work in bra/ket notation: \begin{align*} \left|{\psi}\right\rangle &=\sum_{n=1}^{\infty}\sum_{m=1}^{\infty}\, c_{nm}\left|{n}\right\rangle \left|{m}\right\rangle \\ &=\sum_{n=1}^{\infty}\sum_{m=1}^{\infty}\, c_{nm}\left|{nm}\right\rangle \end{align*}

  4. Find a formula for the \(c_{nm}\)s in part (b). Find the formula first in bra ket notation and then rewrite it in wave function notation.

group Small Group Activity

30 min.

Operators & Functions
Quantum Fundamentals 2022 (3 years) Students are asked to:
  • Test to see if one of the given functions is an eigenfunction of the given operator
  • See if they can write the functions that are found not to be eigenfunctions as a linear combination of eigenfunctions.

keyboard Computational Activity

120 min.

Position operator
Computational Physics Lab II 2022

quantum mechanics operator matrix element particle in a box eigenfunction

Students find matrix elements of the position operator \(\hat x\) in a sinusoidal basis. This allows them to express this operator as a matrix, which they can then numerically diagonalize and visualize the eigenfunctions.

computer Mathematica Activity

30 min.

Visualization of Quantum Probabilities for a Particle Confined to a Ring
Central Forces 2023 (3 years)

central forces quantum mechanics angular momentum probability density eigenstates time evolution superposition mathematica

Quantum Ring Sequence

Students see probability density for eigenstates and linear combinations of eigenstates for a particle on a ring. The three visual representations: standard position vs probability density plot, a ring with colormapping, and cylindrical plot with height and colormapping, are also animated to visualize time-evolution.

group Small Group Activity

30 min.

Superposition States for a Particle on a Ring

central forces quantum mechanics eigenstates eigenvalues quantum measurements angular momentum hermitian operators probability superposition

Quantum Ring Sequence

Students calculate probabilities for a particle on a ring whose wavefunction is not easily separated into eigenstates by inspection. To find the energy, angular momentum, and position probabilities, students perform integrations with the wavefunction or decompose the wavefunction into a superposition of eigenfunctions.

keyboard Computational Activity

120 min.

Kinetic energy
Computational Physics Lab II 2022

finite difference hamiltonian quantum mechanics particle in a box eigenfunctions

Students implement a finite-difference approximation for the kinetic energy operator as a matrix, and then use numpy to solve for eigenvalues and eigenstates, which they visualize.

group Small Group Activity

30 min.

Wavefunctions on a Quantum Ring
Central Forces 2023 (2 years)

group Small Group Activity

30 min.

Energy and Angular Momentum for a Quantum Particle on a Ring

central forces quantum mechanics eigenstates eigenvalues quantum measurements angular momentum energy hermitian operators probability superposition representations notations degeneracy

Quantum Ring Sequence

Students calculate probabilities for a particle on a ring using three different notations: Dirac bra-ket, matrix, and wave function. After calculating the angular momentum and energy measurement probabilities, students compare their calculation methods for notation.

assignment Homework

Working with Representations on the Ring
Central Forces 2023 (3 years)

The following are 3 different representations for the \(\textbf{same}\) state on a quantum ring for \(r_0=1\) \begin{equation} \left|{\Phi_a}\right\rangle = i\sqrt{\frac{ 2}{12}}\left|{3}\right\rangle - \sqrt{\frac{ 1}{12}}\left|{1}\right\rangle +\sqrt{\frac{ 3}{12}}e^{i\frac{\pi}{4}}\left|{0}\right\rangle -i\sqrt{\frac{ 2}{ 12}}\left|{-1}\right\rangle +\sqrt{\frac{ 4}{12}}\left|{-3}\right\rangle \end{equation} \begin{equation} \left| \Phi_b\right\rangle \doteq \left( \begin{matrix} \vdots \\ i\sqrt{\frac{ 2}{12}}\\ 0 \\ -\sqrt{\frac{ 1}{12}} \\ \sqrt{\frac{ 3}{12}}e^{i\frac{\pi}{4}} \\ -i\sqrt{\frac{ 2}{12}}\\ 0 \\ \sqrt{\frac{4}{12} }\\ \vdots \end{matrix}\right) \begin{matrix} \leftarrow m=0 \end{matrix} \end{equation} \begin{equation} \Phi_c(\phi) \doteq \sqrt{\frac{1}{24 \pi}} \left( i\sqrt{2}e^{i 3 \phi} -e^{i\phi} +\sqrt{3}e^{i\frac{\pi}{4}} -i \sqrt{2} e^{-i\phi} + \sqrt{4}e^{-i 3 \phi} \right) \end{equation}

  1. With each representation of the state given above, explicitly calculate the probability that \(L_z=-1\hbar\). Then, calculate all other non-zero probabilities for values of \(L_z\) with a method/representation of your choice.
  2. Explain how you could be sure you calculated all of the non-zero probabilities.
  3. If you measured the \(z\)-component of angular momentum to be \(3\hbar\), what would the state of the particle be immediately after the measurement is made?
  4. With each representation of the state given above, explicitly calculate the probability that \(E=\frac{9}{2}\frac{\hbar^2}{I}\). Then, calculate all other non-zero probabilities for values of \(E\) with a method of your choice.
  5. If you measured the energy of the state to be \(\frac{9}{2}\frac{\hbar^2}{I}\), what would the state of the particle be immediately after the measurement is made?

face Lecture

120 min.

Ideal Gas
Thermal and Statistical Physics 2020

ideal gas particle in a box grand canonical ensemble chemical potential statistical mechanics

These notes from week 6 of Thermal and Statistical Physics cover the ideal gas from a grand canonical standpoint starting with the solutions to a particle in a three-dimensional box. They include a number of small group activities.