Isothermal/Adiabatic Compressibility

    • assignment Adiabatic Compression

      assignment Homework

      Adiabatic Compression
      ideal gas internal energy engine Energy and Entropy 2020

      A diesel engine requires no spark plug. Rather, the air in the cylinder is compressed so highly that the fuel ignites spontaneously when sprayed into the cylinder.

      In this problem, you may treat air as an ideal gas, which satisfies the equation \(pV = Nk_BT\). You may also use the property of an ideal gas that the internal energy depends only on the temperature \(T\), i.e. the internal energy does not change for an isothermal process. For air at the relevant range of temperatures the heat capacity at fixed volume is given by \(C_V=\frac52Nk_B\), which means the internal energy is given by \(U=\frac52Nk_BT\).

      Note: in this problem you are expected to use only the equations given and fundamental physics laws. Looking up the formula in a textbook is not considered a solution at this level.

      1. If the air is initially at room temperature (taken as \(20^{o}C\)) and is then compressed adiabatically to \(\frac1{15}\) of the original volume, what final temperature is attained (before fuel injection)?

      2. By what factor does the pressure increase?

    • assignment Paramagnet (multiple solutions)

      assignment Homework

      Paramagnet (multiple solutions)
      Energy and Entropy 2021 (2 years) We have the following equations of state for the total magnetization \(M\), and the entropy \(S\) of a paramagnetic system: \begin{align} M&=N\mu\, \frac{e^{\frac{\mu B}{k_B T}} - e^{-\frac{\mu B}{k_B T}}} {e^{\frac{\mu B}{k_B T}} + e^{-\frac{\mu B}{k_B T}}}\\ S&=Nk_B\left\{\ln 2 + \ln \left(e^{\frac{\mu B}{k_B T}}+e^{-\frac{\mu B}{k_B T}}\right) +\frac{\mu B}{k_B T} \frac{e^{\frac{\mu B}{k_B T}} - e^{-\frac{\mu B}{k_B T}}} {e^{\frac{\mu B}{k_B T}} + e^{-\frac{\mu B}{k_B T}}} \right\} \end{align}
      1. List variables in their proper positions in the middle columns of the charts below.

      2. Solve for the magnetic susceptibility, which is defined as: \[\chi_B=\left(\frac{\partial M}{\partial B}\right)_T \]

      3. Using both the differentials (zapping with d) and chain rule diagram methods, find a chain rule for:

        \[\left(\frac{\partial M}{\partial B}\right)_S \]

      4. Evaluate your chain rule. Sense-making: Why does this come out to zero?

    • group Paramagnet (multiple solutions)

      group Small Group Activity

      30 min.

      Paramagnet (multiple solutions)
      • Students evaluate two given partial derivatives from a system of equations.
      • Students learn/review generalized Leibniz notation.
      • Students may find it helpful to use a chain rule diagram.
    • assignment Isolength and Isoforce Stretchability

      assignment Homework

      Isolength and Isoforce Stretchability
      Energy and Entropy 2021 (2 years)

      In class, you measured the isolength stretchability and the isoforce stretchability of your systems in the PDM. We found that for some systems these were very different, while for others they were identical.

      Show with algebra (NOT experiment) that the ratio of isolength stretchability to isoforce stretchability is the same for both the left-hand side of the system and the right-hand side of the system. i.e.: \begin{align} \frac{\left(\frac{\partial {x_L}}{\partial {F_L}}\right)_{x_R}}{\left(\frac{\partial {x_L}}{\partial {F_L}}\right)_{F_R}} &= \frac{\left(\frac{\partial {x_R}}{\partial {F_R}}\right)_{x_L}}{\left(\frac{\partial {x_R}}{\partial {F_R}}\right)_{F_L}} \label{eq:ratios} \end{align}

      Hint
      You will need to make use of the cyclic chain rule: \begin{align} \left(\frac{\partial {A}}{\partial {B}}\right)_{C} = -\left(\frac{\partial {A}}{\partial {C}}\right)_{B}\left(\frac{\partial {C}}{\partial {B}}\right)_{A} \end{align}
      Hint
      You will also need the ordinary chain rule: \begin{align} \left(\frac{\partial {A}}{\partial {B}}\right)_{D} = \left(\frac{\partial {A}}{\partial {C}}\right)_{D}\left(\frac{\partial {C}}{\partial {B}}\right)_{D} \end{align}

    • assignment Rubber Sheet

      assignment Homework

      Rubber Sheet
      Energy and Entropy 2021 (2 years)

      Consider a hanging rectangular rubber sheet. We will consider there to be two ways to get energy into or out of this sheet: you can either stretch it vertically or horizontally. The distance of vertical stretch we will call \(y\), and the distance of horizontal stretch we will call \(x\).

      If I pull the bottom down by a small distance \(\Delta y\), with no horizontal force, what is the resulting change in width \(\Delta x\)? Express your answer in terms of partial derivatives of the potential energy \(U(x,y)\).

    • face Energy and Entropy review

      face Lecture

      5 min.

      Energy and Entropy review
      Thermal and Statistical Physics 2020 (3 years)

      thermodynamics statistical mechanics

      This very quick lecture reviews the content taught in Energy and Entropy, and is the first content in Thermal and Statistical Physics.
    • assignment Bottle in a Bottle 2

      assignment Homework

      Bottle in a Bottle 2
      heat entropy ideal gas Energy and Entropy 2021 (2 years)

      Consider the bottle in a bottle problem in a previous problem set, summarized here.

      A small bottle of helium is placed inside a large bottle, which otherwise contains vacuum. The inner bottle contains a slow leak, so that the helium leaks into the outer bottle. The inner bottle contains one tenth the volume of the outer bottle, which is insulated.

      The volume of the small bottle is 0.001 m23 and the volume of the big bottle is 0.01 m3. The initial state of the gas in the small bottle was \(p=106\) Pa and its temperature \(T=300\) K. Approximate the helium gas as an ideal gas of equations of state \(pV=Nk_BT\) and \(U=\frac32 Nk_BT\).

      1. How many molecules of gas does the large bottle contain? What is the final temperature of the gas?

      2. Compute the integral \(\int \frac{{\mathit{\unicode{273}}} Q}{T}\) and the change of entropy \(\Delta S\) between the initial state (gas in the small bottle) and the final state (gas leaked in the big bottle).

      3. Discuss your results.

    • group Generalized Leibniz Notation

      group Small Group Activity

      10 min.

      Generalized Leibniz Notation
      Static Fields 2022 (5 years) This short small group activity introduces students to the Leibniz notation used for partial derivatives in thermodynamics; unlike standard Leibniz notation, this notation explicitly specifies constant variables. Students are guided in linking the variables from a contextless Leibniz-notation partial derivative to their proper variable categories.
    • assignment Gibbs free energy

      assignment Homework

      Gibbs free energy
      thermodynamics Maxwell relation Energy and Entropy 2020 The Gibbs free energy, \(G\), is given by \begin{align*} G = U + pV - TS. \end{align*}
      1. Find the total differential of \(G\). As always, show your work.
      2. Interpret the coefficients of the total differential \(dG\) in order to find a derivative expression for the entropy \(S\).
      3. From the total differential \(dG\), obtain a different thermodynamic derivative that is equal to \[ \left(\frac{\partial {S}}{\partial {p}}\right)_{T} \]
    • assignment Coffees and Bagels and Net Worth

      assignment Homework

      Coffees and Bagels and Net Worth
      Energy and Entropy 2021 (2 years)

      In economics, the term utility is roughly related to overall happiness. Many things affect your happiness, including the amount of money you have and the amount of coffee you drink. We cannot directly measure your happiness, but we can measure how much money you are willing to give up in order to obtain coffee or bagels. If we assume you choose wisely, we can thus determine that your happiness increases when you decrease your amount of money by that amount in exchange for increasing your coffee consumption. Thus money is a (poor) measure of happiness or utility.

      Money is also a nice quantity because it is conserved---just like energy! You may gain or lose money, but you always do so by a transaction. (There are some exceptions to the conservation of money, but they involve either the Fed, counterfeiters, or destruction of cash money, and we will ignore those issues.)

      In this problem, we will assume that you have bought all the coffee and bagels you want (and no more), so that your happiness has been maximized. Thus you are in equilibrium with the coffee shop. We will assume further that you remain in equilibrium with the coffee shop at all times, and that you can sell coffee and bagels back to the coffee shop at cost.*

      Thus your savings \(S\) can be considered to be a function of your bagels \(B\) and coffee \(C\). In this problem we will also discuss the prices \(P_B\) and \(P_C\), which you may not assume are independent of \(B\) and \(C\). It may help to imagine that you could possibly buy out the local supply of coffee, and have to import it at higher costs.

      1. The prices of bagels and coffee \(P_B\) and \(P_C\) have derivative relationships between your savings and the quantity of coffee and bagels that you have. What are the units of these prices? What is the mathematical definition of \(P_C\) and \(P_B\)?

      2. Write down the total differential of your savings, in terms of \(B\), \(C\), \(P_B\) and \(P_C\).

      3. Solve for the total differential of your net worth. Your net worth \(W\) is the sum of your total savings plus the value of the coffee and bagels that you own. From the total differential, relate your amount of coffee and bagels to partial derivatives of your net worth.

  • Energy and Entropy 2021 (2 years)

    The isothermal compressibility is defined as \begin{equation} K_{T}=-\frac{1}{V} \left(\frac{\partial V}{\partial p}\right)_{T} \end{equation} \(K_T\) is be found by measuring the fractional change in volume when the the pressure is slightly changed with the temperature held constant. In contrast, the adiabatic compressibility is defined as \begin{equation} K_{S}=-\frac{1}{V} \left(\frac{\partial V}{\partial p}\right)_{S} \end{equation} and is measured by making a slight change in pressure without allowing for any heat transfer. This is the compressibility, for instance, that would directly affect the speed of sound. Show that \begin{equation} \frac{K_{T}}{K_{S}} = \frac{C_{p}}{C_{V}} \end{equation} Where the heat capacities at constant pressure and volume are given by \begin{align} C_{p} &= T \left(\frac{\partial S}{\partial T}\right)_{p} \\ C_{V} &= T \left(\frac{\partial S}{\partial T}\right)_{V} \end{align}