format_list_numbered Sequence

Quantum Ring Sequence
Students calculate probabilities and expectation values for a quantum mechanical particle confined to a circular ring in bra/ket, matrix, and wave function representations and compare the different calculation methods. Several different graphical representations of the time dependence for both states with special symmetry and arbitrary states are explored in a Mathematica notebook. Compared to the analogous particle-in-a-box, this quantum system has a new feature---degenerate energy eigenstates.

assignment Homework

Gibbs entropy is extensive
Gibbs entropy Probability Thermal and Statistical Physics 2020

Consider two noninteracting systems \(A\) and \(B\). We can either treat these systems as separate, or as a single combined system \(AB\). We can enumerate all states of the combined by enumerating all states of each separate system. The probability of the combined state \((i_A,j_B)\) is given by \(P_{ij}^{AB} = P_i^AP_j^B\). In other words, the probabilities combine in the same way as two dice rolls would, or the probabilities of any other uncorrelated events.

  1. Show that the entropy of the combined system \(S_{AB}\) is the sum of entropies of the two separate systems considered individually, i.e. \(S_{AB} = S_A+S_B\). This means that entropy is extensive. Use the Gibbs entropy for this computation. You need make no approximation in solving this problem.
  2. Show that if you have \(N\) identical non-interacting systems, their total entropy is \(NS_1\) where \(S_1\) is the entropy of a single system.

Note
In real materials, we treat properties as being extensive even when there are interactions in the system. In this case, extensivity is a property of large systems, in which surface effects may be neglected.

assignment Homework

Ring Table
Central Forces 2023 (3 years)

Attached, you will find a table showing different representations of physical quantities associated with a quantum particle confined to a ring. Fill in all of the missing entries. Hint: You may look ahead. We filled out a number of the entries throughout the table to give you hints about what the forms of the other entries might be. pdf link for the Table or doc link for the Table

group Small Group Activity

30 min.

Superposition States for a Particle on a Ring

central forces quantum mechanics eigenstates eigenvalues quantum measurements angular momentum hermitian operators probability superposition

Quantum Ring Sequence

Students calculate probabilities for a particle on a ring whose wavefunction is not easily separated into eigenstates by inspection. To find the energy, angular momentum, and position probabilities, students perform integrations with the wavefunction or decompose the wavefunction into a superposition of eigenfunctions.

computer Mathematica Activity

30 min.

Visualization of Quantum Probabilities for the Hydrogen Atom
Central Forces 2023 (3 years) Students use Mathematica to visualize the probability density distribution for the hydrogen atom orbitals with the option to vary the values of \(n\), \(\ell\), and \(m\).

assignment Homework

Symmetry of filled and vacant orbitals
Symmetry Orbitals Thermal and Statistical Physics 2020 Show that \begin{align} f(\mu+\delta) &= 1 - f(\mu-\delta) \end{align} This means that the probability that an orbital above the Fermi level is occupied is equal to the probability an orbital the same distance below the Fermi level being empty. These unoccupied orbitals are called holes.

group Small Group Activity

30 min.

Time Evolution of a Spin-1/2 System
Quantum Fundamentals 2022 (3 years)

quantum mechanics spin precession time evolution

In this small group activity, students solve for the time dependence of two quantum spin 1/2 particles under the influence of a Hamiltonian. Students determine, given a Hamiltonian, which states are stationary and under what circumstances measurement probabilities do change with time.

group Small Group Activity

30 min.

Quantum Measurement Play
Quantum Fundamentals 2022 (2 years)

Quantum Measurement Projection Operators Spin-1/2

The instructor and students do a skit where students represent quantum states that are “measured” by the instructor resulting in a state collapse.

assignment Homework

Wavefunctions
Quantum Fundamentals 2022 (2 years)

Consider the following wave functions (over all space - not the infinite square well!):

\(\psi_a(x) = A e^{-x^2/3}\)

\(\psi_b(x) = B \frac{1}{x^2+2} \)

\(\psi_c(x) = C \;\mbox{sech}\left(\frac{x}{5}\right)\) (“sech” is the hyperbolic secant function.)

In each case:

  1. normalize the wave function,
  2. plot the wave function using Mathematica or other computer plotting tool (be sure to include the code you used and label your plots/axes appropriately),
  3. find the probability that the particle is measured to be in the range \(0<x<1\).

computer Mathematica Activity

30 min.

Visualizing Combinations of Spherical Harmonics
Central Forces 2023 (3 years) Students observe three different plots of linear combinations of spherical combinations with probability density represented by color on the sphere, distance from the origin (polar plot), and distance from the surface of the sphere.

group Small Group Activity

10 min.

Sequential Stern-Gerlach Experiments
Quantum Fundamentals 2022 (3 years)

assignment Homework

Phase 2
quantum mechanics relative phase overall phase measurement probability Quantum Fundamentals 2022 (2 years) Consider the three quantum states: \[\left\vert \psi_1\right\rangle = \frac{4}{5}\left\vert +\right\rangle+ i\frac{3}{5} \left\vert -\right\rangle\] \[\left\vert \psi_2\right\rangle = \frac{4}{5}\left\vert +\right\rangle- i\frac{3}{5} \left\vert -\right\rangle\] \[\left\vert \psi_3\right\rangle = -\frac{4}{5}\left\vert +\right\rangle+ i\frac{3}{5} \left\vert -\right\rangle\]
  1. For each of the \(\left|{\psi_i}\right\rangle \) above, calculate the probabilities of spin component measurements along the \(x\), \(y\), and \(z\)-axes.
  2. Look For a Pattern (and Generalize): Use your results from \((a)\) to comment on the importance of the overall phase and of the relative phases of the quantum state vector.

group Small Group Activity

30 min.

Time Dependence for a Quantum Particle on a Ring
Theoretical Mechanics (6 years)

central forces quantum mechanics eigenstates eigenvalues angular momentum time dependence hermitian operators probability degeneracy quantum measurements

Quantum Ring Sequence

Students calculate probabilities for energy, angular momentum, and position as a function of time for an initial state that is a linear combination of energy/angular momentum eigenstates for a particle confined to a ring written in bra-ket notation. This activity helps students build an understanding of when they can expect a quantity to depend on time and to give them more practice moving between representations.

group Small Group Activity

60 min.

Going from Spin States to Wavefunctions
Quantum Fundamentals 2022 (2 years)

Wavefunctions quantum states probability amplitude histograms matrix notation of quantum states Arms representation

Arms Sequence for Complex Numbers and Quantum States

Students review using the Arms representation to represent states for discrete quantum systems and connecting the Arms representation to histogram and matrix representation. The student then extend the Arms representation to begin exploring the continuous position basis.

group Small Group Activity

30 min.

Wavefunctions on a Quantum Ring
Central Forces 2023 (2 years)

assignment Homework

Boltzmann probabilities
Energy Entropy Boltzmann probabilities Thermal and Statistical Physics 2020 (3 years) Consider a three-state system with energies \((-\epsilon,0,\epsilon)\).
  1. At infinite temperature, what are the probabilities of the three states being occupied? What is the internal energy \(U\)? What is the entropy \(S\)?
  2. At very low temperature, what are the three probabilities?
  3. What are the three probabilities at zero temperature? What is the internal energy \(U\)? What is the entropy \(S\)?
  4. What happens to the probabilities if you allow the temperature to be negative?

group Small Group Activity

60 min.

Expectation Value and Uncertainty for the Difference of Dice
Quantum Fundamentals 2022 (3 years)

group Small Group Activity

30 min.

Working with Representations on the Ring
Central Forces 2023 (3 years)

assignment Homework

Visualization of Wave Functions on a Ring
Central Forces 2023 (3 years) Using either this Geogebra applet or this Mathematica notebook, explore the wave functions on a ring. (Note: The Geogebra applet may be a little easier to use and understand and is accessible if you don't have access to Mathematica, but it is more limited in the wave functions that you can represent. Also, the animation is pretty jumpy in some browsers, especially Firefox. Imagine that the motion is smooth.)
  1. Look at graphs of the following states \begin{align} \Phi_1(\phi)&=\frac{1}{\sqrt{2}}(\left|{2}\right\rangle +\left|{-2}\right\rangle )\\ \Phi_2(\phi)&=\frac{1}{\sqrt{2}}(\left|{2}\right\rangle -\left|{-2}\right\rangle )\\ \Phi_3(\phi)&=\frac{1}{\sqrt{2}}(\left|{2}\right\rangle +i\left|{-2}\right\rangle ) \end{align} Write a short description of how these states differ from each other.
  2. Find a state for which the probability density does not depend on time. Write the state in both ket and wave function notation. These are called stationary states. Generalize your result to give a characterization of the set of all possible states that are stationary states.
  3. Find a state that is right-moving. Write the state in both ket and wave function notation. Generalize your result to give a characterization of the set of all possible states that are right-moving.
  4. Find a state that is a standing wave. Write the state in both ket and wave function notation. Generalize your result to give a characterization of the set of all possible states that are standing waves.

keyboard Computational Activity

120 min.

Mean position
Computational Physics Lab II 2022

probability density particle in a box wave function quantum mechanics

Students compute probabilities and averages given a probability density in one dimension. This activity serves as a soft introduction to the particle in a box, introducing all the concepts that are needed.