computer Mathematica Activity

30 min.

Visualization of Quantum Probabilities for the Hydrogen Atom
Central Forces 2023 (3 years) Students use Mathematica to visualize the probability density distribution for the hydrogen atom orbitals with the option to vary the values of \(n\), \(\ell\), and \(m\).

assignment Homework

Diatomic hydrogen
rigid rotor hamiltonian angular momentum ground state hydrogen diatomic probability Energy and Entropy 2021 (2 years)

At low temperatures, a diatomic molecule can be well described as a rigid rotor. The Hamiltonian of such a system is simply proportional to the square of the angular momentum \begin{align} H &= \frac{1}{2I}L^2 \end{align} and the energy eigenvalues are \begin{align} E_{\ell m} &= \hbar^2 \frac{\ell(\ell+1)}{2I} \end{align}

  1. What is the energy of the ground state and the first and second excited states of the \(H_2\) molecule? i.e. the lowest three distinct energy eigenvalues.

  2. At room temperature, what is the relative probability of finding a hydrogen molecule in the \(\ell=0\) state versus finding it in any one of the \(\ell=1\) states?
    i.e. what is \(P_{\ell=0,m=0}/\left(P_{\ell=1,m=-1} + P_{\ell=1,m=0} + P_{\ell=1,m=1}\right)\)

  3. At what temperature is the value of this ratio 1?

  4. At room temperature, what is the probability of finding a hydrogen molecule in any one of the \(\ell=2\) states versus that of finding it in the ground state?
    i.e. what is \(P_{\ell=0,m=0}/\left(P_{\ell=2,m=-2} + P_{\ell=2,m=-1} + \cdots + P_{\ell=2,m=2}\right)\)

group Small Group Activity

30 min.

Hydrogen emission
Contemporary Challenges 2022 (5 years)

hydrogen atom photon energy

In this activity students work out energy level transitions in hydrogen that lead to visible light.

assignment Homework

Spin Fermi Estimate
Quantum Fundamentals 2022 The following two problems ask you to make Fermi estimates. In a good Fermi estimate, you start from basic scientific facts you already know or quantities that you can reasonably estimate based on your life experiences and then reason your way to estimate a quantity that you would not be able guess. You may look up useful conversion factors or constants. Use words, pictures, and equations to explain your reasoning:
  1. Imagine that you send a pea-sized bead of silver through a Stern-Gerlach device oriented to measure the z-component of intrinsic spin. Estimate the total z-component of the intrinsic spin of the ball you would measure in the HIGHLY improbable case that every atom is spin up.
  2. Protons, neutrons, and electrons are all spin-1/2 particles. Give a (very crude) order of magnitude estimate of the number of these particles in your body.

assignment Homework

Mass-radius relationship for white dwarfs
White dwarf Mass Density Energy Thermal and Statistical Physics 2020

Consider a white dwarf of mass \(M\) and radius \(R\). The dwarf consists of ionized hydrogen, thus a bunch of free electrons and protons, each of which are fermions. Let the electrons be degenerate but nonrelativistic; the protons are nondegenerate.

  1. Show that the order of magnitude of the gravitational self-energy is \(-\frac{GM^2}{R}\), where \(G\) is the gravitational constant. (If the mass density is constant within the sphere of radius \(R\), the exact potential energy is \(-\frac53\frac{GM^2}{R}\)).

  2. Show that the order of magnitude of the kinetic energy of the electrons in the ground state is \begin{align} \frac{\hbar^2N^{\frac53}}{mR^2} \approx \frac{\hbar^2M^{\frac53}}{mM_H^{\frac53}R^2} \end{align} where \(m\) is the mass of an electron and \(M_H\) is the mas of a proton.

  3. Show that if the gravitational and kinetic energies are of the same order of magnitude (as required by the virial theorem of mechanics), \(M^{\frac13}R \approx 10^{20} \text{g}^{\frac13}\text{cm}\).

  4. If the mass is equal to that of the Sun (\(2\times 10^{33}g\)), what is the density of the white dwarf?

  5. It is believed that pulsars are stars composed of a cold degenerate gas of neutrons (i.e. neutron stars). Show that for a neutron star \(M^{\frac13}R \approx 10^{17}\text{g}^{\frac13}\text{cm}\). What is the value of the radius for a neutron star with a mass equal to that of the Sun? Express the result in \(\text{km}\).

assignment Homework

Potential vs. Potential Energy
Static Fields 2022 (5 years)

In this course, two of the primary examples we will be using are the potential due to gravity and the potential due to an electric charge. Both of these forces vary like \(\frac{1}{r}\), so they will have many, many similarities. Most of the calculations we do for the one case will be true for the other. But there are some extremely important differences:

  1. Find the value of the electrostatic potential energy of a system consisting of a hydrogen nucleus and an electron separated by the Bohr radius. Find the value of the gravitational potential energy of the same two particles at the same radius. Use the same system of units in both cases. Compare and the contrast the two answers.
  2. Find the value of the electrostatic potential due to the nucleus of a hydrogen atom at the Bohr radius. Find the gravitational potential due to the nucleus at the same radius. Use the same system of units in both cases. Compare and contrast the two answers.
  3. Briefly discuss at least one other fundamental difference between electromagnetic and gravitational systems. Hint: Why are we bound to the earth gravitationally, but not electromagnetically?

assignment Homework

Heat of vaporization of ice
Vaporization Heat Thermal and Statistical Physics 2020 The pressure of water vapor over ice is 518 Pa at \(-2^\circ\text{C}\). The vapor pressure of water at its triple point is 611 Pa, at 0.01\(^\circ\text{C}\) (see Estimate in \(\text{J mol}^{-1}\) the heat of vaporization of ice just under freezing. How does this compare with the heat of vaporization of water?

computer Mathematica Activity

30 min.

Visualization of Quantum Probabilities for a Particle Confined to a Ring
Central Forces 2023 (3 years)

central forces quantum mechanics angular momentum probability density eigenstates time evolution superposition mathematica

Quantum Ring Sequence

Students see probability density for eigenstates and linear combinations of eigenstates for a particle on a ring. The three visual representations: standard position vs probability density plot, a ring with colormapping, and cylindrical plot with height and colormapping, are also animated to visualize time-evolution.

assignment Homework

Potential energy of gas in gravitational field
Potential energy Heat capacity Thermal and Statistical Physics 2020 Consider a column of atoms each of mass \(M\) at temperature \(T\) in a uniform gravitational field \(g\). Find the thermal average potential energy per atom. The thermal average kinetic energy is independent of height. Find the total heat capacity per atom. The total heat capacity is the sum of contributions from the kinetic energy and from the potential energy. Take the zero of the gravitational energy at the bottom \(h=0\) of the column. Integrate from \(h=0\) to \(h=\infty\). You may assume the gas is ideal.

computer Mathematica Activity

30 min.

Visualizing Combinations of Spherical Harmonics
Central Forces 2023 (3 years) Students observe three different plots of linear combinations of spherical combinations with probability density represented by color on the sphere, distance from the origin (polar plot), and distance from the surface of the sphere.

group Small Group Activity

30 min.

Hydrogen Probabilities in Matrix Notation
Central Forces 2023 (2 years)

face Lecture

5 min.

Central Forces Introduction: Lecture Notes
Central Forces 2023 (2 years)

face Lecture

5 min.

Quantum Reference Sheet
Central Forces 2023 (6 years)

group Small Group Activity

30 min.

Energy and Angular Momentum for a Quantum Particle on a Ring

central forces quantum mechanics eigenstates eigenvalues quantum measurements angular momentum energy hermitian operators probability superposition representations notations degeneracy

Quantum Ring Sequence

Students calculate probabilities for a particle on a ring using three different notations: Dirac bra-ket, matrix, and wave function. After calculating the angular momentum and energy measurement probabilities, students compare their calculation methods for notation.