Activities
These lecture notes from the ninth week of https://paradigms.oregonstate.edu/courses/ph441 cover phase transformations, the Clausius-Clapeyron relation, mean field theory and more. They include a number of small group activities.
Problem
Consider a phase transformation between either solid or liquid and gas. Assume that the volume of the gas is way bigger than that of the liquid or solid, such that \(\Delta V \approx V_g\). Furthermore, assume that the ideal gas law applies to the gas phase. Note: this problem is solved in the textbook, in the section on the Clausius-Clapeyron equation.
Solve for \(\frac{dp}{dT}\) in terms of the pressure of the vapor and the latent heat \(L\) and the temperature.
Assume further that the latent heat is roughly independent of temperature. Integrate to find the vapor pressure itself as a function of temperature (and of course, the latent heat).
Calculate based on the Clausius-Clapeyron equation the value of \(\frac{dT}{dp}\) near \(p=1\text{atm}\) for the liquid-vapor equilibrium of water. The heat of vaporization at \(100^\circ\text{C}\) is \(2260\text{ J g}^{-1}\). Express the result in kelvin/atm.