Homework Problems

Consider the finite line with a uniform charge density from class.

1. Write an integral expression for the electric field at any point in space due to the finite line. In addition to your usual physics sense-making, you must include a clearly labeled figure and discuss what happens to the direction of the unit vectors as you integrate.Consider the finite line with a uniform charge density from class.
2. Perform the integral to find the \(z\)-component of the electric field. In addition to your usual physics sense-making, you must compare your result to the gradient of the electric potential we found in class. (If you want to challenge yourself, do the \(s\)-component as well!)

For electrons with an energy \(\varepsilon\gg mc^2\), where \(m\) is the mass of the electron, the energy is given by \(\varepsilon\approx pc\) where \(p\) is the momentum. For electrons in a cube of volume \(V=L^3\) the momentum takes the same values as for a non-relativistic particle in a box.

1. Show that in this extreme relativistic limit the Fermi energy of a gas of \(N\) electrons is given by \begin{align} \varepsilon_F &= \hbar\pi c\left(\frac{3n}{\pi}\right)^{\frac13} \end{align} where \(n\equiv \frac{N}{V}\) is the number density.

2. Show that the total energy of the ground state of the gas is \begin{align} U_0 &= \frac34 N\varepsilon_F \end{align}

The goal of this problem is to show that once we have maximized the entropy and found the microstate probabilities in terms of a Lagrange multiplier \(\beta\), we can prove that \(\beta=\frac1{kT}\) based on the statistical definitions of energy and entropy and the thermodynamic definition of temperature embodied in the thermodynamic identity.

The internal energy and entropy are each defined as a weighted average over microstates: \begin{align} U &= \sum_i E_i P_i & S &= -k_B\sum_i P_i \ln P_i \end{align}: We saw in clase that the probability of each microstate can be given in terms of a Lagrange multiplier \(\beta\) as \begin{align} P_i &= \frac{e^{-\beta E_i}}{Z} & Z &= \sum_i e^{-\beta E_i} \end{align} Put these probabilities into the above weighted averages in order to relate \(U\) and \(S\) to \(\beta\). Then make use of the thermodynamic identity \begin{align} dU = TdS - pdV \end{align} to show that \(\beta = \frac1{kT}\).

The goal of this problem is to show that once we have maximized the entropy and found the microstate probabilities in terms of a Lagrange multiplier \(\beta\), we can prove that \(\beta=\frac1{kT}\) based on the statistical definitions of energy and entropy and the thermodynamic definition of temperature embodied in the thermodynamic identity.

The internal energy and entropy are each defined as a weighted average over microstates: \begin{align} U &= \sum_i E_i P_i & S &= -k_B\sum_i P_i \ln P_i \end{align} We saw in clase that the probability of each microstate can be given in terms of a Lagrange multiplier \(\beta\) as \begin{align} P_i &= \frac{e^{-\beta E_i}}{Z} & Z &= \sum_i e^{-\beta E_i} \end{align} Put these probabilities into the above weighted averages in order to relate \(U\) and \(S\) to \(\beta\). Then make use of the thermodynamic identity \begin{align} dU = TdS - pdV \end{align} to show that \(\beta = \frac1{kT}\).

Suppose \(g(U) = CU^{3N/2}\), where \(C\) is a constant and \(N\) is the number of particles.

1. Show that \(U=\frac32 N k_BT\).

2. Show that \(\left(\frac{\partial^2S}{\partial U^2}\right)_N\) is negative. This form of \(g(U)\) actually applies to a monatomic ideal gas.

Suppose that a system of \(N\) atoms of type \(A\) is placed in diffusive contact with a system of \(N\) atoms of type \(B\) at the same temperature and volume.

1. Show that after diffusive equilibrium is reached the total entropy is increased by \(2Nk\ln 2\). The entropy increase \(2Nk\ln 2\) is known as the entropy of mixing.

2. If the atoms are identical (\(A=B\)), show that there is no increase in entropy when diffusive contact is established. The difference has been called the Gibbs paradox.

3. Since the Helmholtz free energy is lower for the mixed \(AB\) than for the separated \(A\) and \(B\), it should be possible to extract work from the mixing process. Construct a process that could extract work as the two gasses are mixed at fixed temperature. You will probably need to use walls that are permeable to one gas but not the other.

Note

This course has not yet covered work, but it was covered in Energy and Entropy, so you may need to stretch your memory to finish part (c).

In this entire problem, keep results to first order in the van der Waals correction terms \(a\) and $b.

1. Show that the entropy of the van der Waals gas is \begin{align} S &= Nk\left\{\ln\left(\frac{n_Q(V-Nb)}{N}\right)+\frac52\right\} \end{align}

2. Show that the energy is \begin{align} U &= \frac32 NkT - \frac{N^2a}{V} \end{align}

3. Show that the enthalpy \(H\equiv U+pV\) is \begin{align} H(T,V) &= \frac52NkT + \frac{N^2bkT}{V} - 2\frac{N^2a}{V} \\ H(T,p) &= \frac52NkT + Nbp - \frac{2Nap}{kT} \end{align}

1. 1. Which pairs of events (if any) are simultaneous in the unprimed frame?

   2. Which pairs of events (if any) are simultaneous in the primed frame?

   3. Which pairs of events (if any) are colocated in the unprimed frame?

   4. Which pairs of events (if any) are colocated in the primed frame?

      

2. For each of the figures, answer the following questions:

   1. Which event occurs first in the unprimed frame?

   2. Which event occurs first in the primed frame?

      1. 

      2. 

      3. 

Make sure that you have memorized the following identities and can use them in simple algebra problems: \begin{align} e^{u+v}&=e^u \, e^v\\ \ln{uv}&=\ln{u}+\ln{v}\\ u^v&=e^{v\ln{u}} \end{align}

Consider a system which has an internal energy \(U\) defined by: \begin{align} U &= \gamma V^\alpha S^\beta \end{align} where \(\alpha\), \(\beta\) and \(\gamma\) are constants. The internal energy is an extensive quantity. What constraint does this place on the values \(\alpha\) and \(\beta\) may have?

Start with \(d\vec{r}\) in rectangular, cylindrical, and spherical coordinates. Use these expressions to write the scalar area elements \(dA\) (for different coordinate equals constant surfaces) and the volume element \(d\tau\). It might help you to think of the following surfaces: The various sides of a rectangular box, a finite cylinder with a top and a bottom, a half cylinder, and a hemisphere with both a curved and a flat side, and a cone.

1. Rectangular: \begin{align} dA&=\\ d\tau&= \end{align}
2. Cylindrical: \begin{align} dA&=\\ d\tau&= \end{align}
3. Spherical: \begin{align} dA&=\\ d\tau&= \end{align}

(Use the equation for orbit shape.) Gain experience with unusual force laws.

In science fiction movies, characters often talk about a spaceship “spiralling in” right before it hits the planet. But all orbits in a \(1/r^2\) force are conic sections, not spirals. This spiralling in happens because the spaceship hits atmosphere and the drag from the atmosphere changes the shape of the orbit. But, in an alternate universe, we might have other force laws.

Find the force law for a mass \(\mu\), under the influence of a central-force field, that moves in a logarithmic spiral orbit given by \(r = ke^{\alpha \phi}\), where \(k\) and \(\alpha\) are constants.

Find the upward pointing flux of the electric field \(\vec E =E_0\, z\, \hat z\) through the part of the surface \(z=-3 s^2 +12\) (cylindrical coordinates) that sits above the \((x, y)\)--plane.

• Set up the integrals for the Fourier series for this state.

• Which terms will have the largest coefficients? Explain briefly.

• Are there any coefficients that you know will be zero? Explain briefly.

• Using the technology of your choice or by hand, calculate the four largest coefficients. With screen shots or otherwise, show your work.

• Using the technology of your choice, plot the ground state and your approximation on the same axes.

1. Find the Fourier transforms of \(f(x)=\cos kx\) and \(g(x)=\sin kx\).
2. Find the Fourier transform of \(g(x)\) using the formula for the Fourier transform of a derivative and your result for the Fourier transform of \(f(x)\). Compare with your previous answer.
3. In quantum mechanics, the Fourier transform is the set of coefficients in the expansion of a quantum state in terms of plane waves, i.e. the function \(\tilde{f}(k)\) is a continuous histogram of how much each functions \(e^{ikx}\) contributes to the quantum state. What does the Fourier transform of the function \(\cos kx\) tell you about which plane waves make up this quantum state? Write a sentence or two about how this makes sense.

A one-dimensional harmonic oscillator has an infinite series of equally spaced energy states, with \(\varepsilon_n = n\hbar\omega\), where \(n\) is an integer \(\ge 0\), and \(\omega\) is the classical frequency of the oscillator. We have chosen the zero of energy at the state \(n=0\) which we can get away with here, but is not actually the zero of energy! To find the true energy we would have to add a \(\frac12\hbar\omega\) for each oscillator.

1. Show that for a harmonic oscillator the free energy is \begin{equation} F = k_BT\log\left(1 - e^{-\frac{\hbar\omega}{k_BT}}\right) \end{equation} Note that at high temperatures such that \(k_BT\gg\hbar\omega\) we may expand the argument of the logarithm to obtain \(F\approx k_BT\log\left(\frac{\hbar\omega}{kT}\right)\).

2. From the free energy above, show that the entropy is \begin{equation} \frac{S}{k_B} = \frac{\frac{\hbar\omega}{kT}}{e^{\frac{\hbar\omega}{kT}}-1} - \log\left(1-e^{-\frac{\hbar\omega}{kT}}\right) \end{equation}

   

   

   This entropy is shown in the nearby figure, as well as the heat capacity.

1. Find an expression for the free energy as a function of \(T\) of a system with two states, one at energy 0 and one at energy \(\varepsilon\).

2. From the free energy, find expressions for the internal energy \(U\) and entropy \(S\) of the system.

3. Plot the entropy versus \(T\). Explain its asymptotic behavior as the temperature becomes high.

4. Plot the \(S(T)\) versus \(U(T)\). Explain the maximum value of the energy \(U\).

The internal energy is of any ideal gas can be written as \begin{align} U &= U(T,N) \end{align} meaning that the internal energy depends only on the number of particles and the temperature, but not the volume.^*

1. What is the change in entropy of the gas? How do you know this?

2. What is the change in temperature of the gas?

Give the general solution of the differential equation: \[\frac{d^2 y}{dx^2}+Ay=0\] Make sure that you can give the solution of this equation regardless of the geometric names of the dependent and independent variables and for either sign for the constant \(A\).

It is NOT necessary to show any work. You may NOT, however, give a solution that has a negative number inside a square root. I am testing whether you can recognize this equation and remember its solution. This equation comes up over and over again in physics, but disguised by different symbols. I am also testing whether you recognize that the geometric character of the equation changes depending on the sign of \(A\).

Give the general solution of the differential equation: \[\frac{d^2 \Phi}{d\phi^2}+7\Phi=0\]

It is NOT necessary to show any work.

Give the general solution of the differential equation: \[\frac{d^2 u}{d\phi^2}+u=0\]

It is NOT necessary to show any work.

Consider two noninteracting systems \(A\) and \(B\). We can either treat these systems as separate, or as a single combined system \(AB\). We can enumerate all states of the combined by enumerating all states of each separate system. The probability of the combined state \((i_A,j_B)\) is given by \(P_{ij}^{AB} = P_i^AP_j^B\). In other words, the probabilities combine in the same way as two dice rolls would, or the probabilities of any other uncorrelated events.

1. Show that the entropy of the combined system \(S_{AB}\) is the sum of entropies of the two separate systems considered individually, i.e. \(S_{AB} = S_A+S_B\). This means that entropy is extensive. Use the Gibbs entropy for this computation. You need make no approximation in solving this problem.
2. Show that if you have \(N\) identical non-interacting systems, their total entropy is \(NS_1\) where \(S_1\) is the entropy of a single system.

Note

1. Find the total differential of \(G\). As always, show your work.
2. Interpret the coefficients of the total differential \(dG\) in order to find a derivative expression for the entropy \(S\).
3. From the total differential \(dG\), obtain a different thermodynamic derivative that is equal to \[ \left(\frac{\partial {S}}{\partial {p}}\right)_{T} \]

1. Consider a system that may be unoccupied with energy zero, or occupied by one particle in either of two states, one of energy zero and one of energy \(\varepsilon\). Find the Gibbs sum for this system is in terms of the activity \(\lambda\equiv e^{\beta\mu}\). Note that the system can hold a maximum of one particle.

2. Solve for the thermal average occupancy of the system in terms of \(\lambda\).

3. Show that the thermal average occupancy of the state at energy \(\varepsilon\) is \begin{align} \langle N(\varepsilon)\rangle = \frac{\lambda e^{-\frac{\varepsilon}{kT}}}{\mathcal{Z}} \end{align}

4. Find an expression for the thermal average energy of the system.

5. Allow the possibility that the orbitals at \(0\) and at \(\varepsilon\) may each be occupied each by one particle at the same time; Show that \begin{align} \mathcal{Z} &= 1 + \lambda + \lambda e^{-\frac{\varepsilon}{kT}} + \lambda^2 e^{-\frac{\varepsilon}{kT}} \\ &= (1+\lambda)\left(1+e^{-\frac{\varepsilon}{kT}}\right) \end{align} Because \(\mathcal{Z}\) can be factored as shown, we have in effect two independent systems.

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Consider the fields at a point \(\vec{r}\) due to a point charge located at \(\vec{r}'\).

1. Write down an expression for the electrostatic potential \(V(\vec{r})\) at a point \(\vec{r}\) due to a point charge located at \(\vec{r}'\). (There is nothing to calculate here.)
2. Write down an expression for the electric field \(\vec{E}(\vec{r})\) at a point \(\vec{r}\) due to a point charge located at \(\vec{r}'\). (There is nothing to calculate here.)
3. Working in rectangular coordinates, compute the gradient of \(V\).
4. Write several sentences comparing your answers to the last two questions.

Find the gradient of each of the following functions:

1. \begin{equation} f(x,y,z)=e^{(x+y)}+x^2 y^3 \ln \frac{x}{z} \end{equation}
2. \begin{equation} \sigma(\theta,\phi)=\cos\theta \sin^2\phi \end{equation}
3. \begin{equation} \rho(s,\phi,z)=(s+3z)^2\cos\phi \end{equation}

Learn more about the geometry of \(\vert \vec{r}-\vec{r'}\vert\) in two dimensions.

1. Make sketches of the following functions, by hand, on the same axes: \begin{align} y &= \sin x\\ y &= \sin(2+x) \end{align} Briefly describe the role that the number 2 plays in the shape of the second graph

2. Make a sketch of the graph \begin{equation} \vert \vec{r} - \vec{a} \vert = 2 \end{equation}

   for each of the following values of \(\vec a\): \begin{align} \vec a &= \vec 0\\ \vec a &= 2 \hat x- 3 \hat y\\ \vec a &= \text{points due east and is 2 units long} \end{align}

3. Derive a more familiar equation equivalent to \begin{equation} \vert \vec r - \vec a \vert = 2 \end{equation} for arbitrary \(\vec a\), by expanding \(\vec r\) and \(\vec a\) in rectangular coordinates. Simplify as much as possible. (Ok, ok, I know this is a terribly worded question. What do I mean by “more familiar"? What do I mean by “simplify as much as possible"? Why am I making you read my mind? Try it anyway. Real life is not full of carefully worded problems. Bonus points to anyone who can figure out a better way of wording the question that doesn't give the point away.)
4. Write a brief description of the geometric meaning of the equation \begin{equation} \vert \vec r - \vec a \vert = 2 \end{equation}

The gravitational field due to a spherical shell of matter (or equivalently, the electric field due to a spherical shell of charge) is given by: \begin{equation} \vec g = \begin{cases} 0&\textrm{for } r<a\\ -G \,\frac{M}{b^3-a^3}\, \left( r-\frac{a^3}{r^2}\right)\, \hat r & \textrm{for } a<r<b\\ -G\,\frac{M}{r^2}\, \hat r & \textrm{for } r>b \\ \end{cases} \end{equation}

This problem explores the consequences of the divergence theorem for this shell.

1. Using the given description of the gravitational field, find the divergence of the gravitational field everywhere in space. You will need to divide this question up into three parts: \(r<a\), \(a<r<b\), and \(r>b\).
2. Briefly discuss the physical meaning of the divergence in this particular example.
3. For this gravitational field, verify the divergence theorem on a sphere, concentric with the shell, with radius \(Q\), where \(a<Q<b\). ("Verify" the divergence theorem means calculate the integrals from both sides of the divergence theorem and show that they give the same answer.)
4. Briefly discuss how this example would change if you were discussing the electric field of a uniformly charged spherical shell.

1. Solve for the heat capacity of a vacuum, given the above, and assuming that photons represent all the energy present in vacuum.
2. Compare the heat capacity of vacuum at room temperature with the heat capacity of an equal volume of water.

1. Show that for a reversible heat pump the energy required per unit of heat delivered inside the building is given by the Carnot efficiency: \begin{align} \frac{W}{Q_H} &= \eta_C = \frac{T_H-T_C}{T_H} \end{align} What happens if the heat pump is not reversible?

2. Assume that the electricity consumed by a reversible heat pump must itself be generated by a Carnot engine operating between the even hotter temperature \(T_{HH}\) and the cold (outdoors) temperature \(T_C\). What is the ratio \(\frac{Q_{HH}}{Q_H}\) of the heat consumed at \(T_{HH}\) (i.e. fuel burned) to the heat delivered at \(T_H\) (in the house we want to heat)? Give numerical values for \(T_{HH}=600\text{K}\); \(T_{H}=300\text{K}\); \(T_{C}=270\text{K}\).

3. Draw an energy-entropy flow diagram for the combination heat engine-heat pump, similar to Figures 8.1, 8.2 and 8.4 in the text (or the equivalent but sloppier) figures in the course notes. However, in this case we will involve no external work at all, only energy and entropy flows at three temperatures, since the work done is all generated from heat.

1. Solve for the net power transferred between the two sheets.

2. A third black metal sheet is inserted between the other two and is allowed to come to a steady state temperature \(T_m\). Find the temperature of the middle sheet, and solve for the new net power transferred between the hot and cold sheets. This is the principle of the heat shield, and is part of how the James Web telescope shield works.

3. Optional: Find the power through an \(N\)-layer sandwich.

A helix with 17 turns has height \(H\) and radius \(R\). Charge is distributed on the helix so that the charge density increases like (i.e. proportional to) the square of the distance up the helix. At the bottom of the helix the linear charge density is \(0~\frac{\textrm{C}}{\textrm{m}}\). At the top of the helix, the linear charge density is \(13~\frac{\textrm{C}}{\textrm{m}}\). What is the total charge on the helix?

(Synthesis Problem: Brings together several different concepts from this unit.) Use effective potential diagrams for other than \(1/r^2\) forces.

Consider the frictionless motion of a hockey puck of mass \(m\) on a perfectly circular bowl-shaped ice rink with radius \(a\). The central region of the bowl (\(r < 0.8a\)) is perfectly flat and the sides of the ice bowl smoothly rise to a height \(h\) at \(r = a\).

1. Draw a sketch of the potential energy for this system. Set the zero of potential energy at the top of the sides of the bowl.
2. Situation 1: the puck is initially moving radially outward from the exact center of the rink. What minimum velocity does the puck need to escape the rink?
3. Situation 2: a stationary puck, at a distance \(\frac{a}{2}\) from the center of the rink, is hit in such a way that it's initial velocity \(\vec v_0\) is perpendicular to its position vector as measured from the center of the rink. What is the total energy of the puck immediately after it is struck?
4. In situation 2, what is the angular momentum of the puck immediately after it is struck?
5. Draw a sketch of the effective potential for situation 2.
6. In situation 2, for what minimum value of \(\vec v_0\) does the puck just escape the rink?

Homogeneous, linear ODEs with constant coefficients were likely covered in your Differential Equations course (MTH 256 or equiv.). If you need a review, please see:

Constant Coefficients, Homogeneous

or your differential equations text.

Answer the following questions for each differential equation below:

• identify the order of the equation,
• find the number of linearly independent solutions,
• find an appropriate set of linearly independent solutions, and
• find the general solution.

1. \(\ddot{x}-\dot{x}-6x=0\)
2. \(y^{\prime\prime\prime}-3y^{\prime\prime}+3y^{\prime}-y=0\)
3. \(\frac{d^2w}{dz^2}-4\frac{dw}{dz}+5w=0\)

1. Plot your data I Plot the temperature versus total energy added to the system (which you can call \(Q\)). To do this, you will need to integrate the power. Discuss this curve and any interesting features you notice on it.
2. Plot your data II Plot the heat capacity versus temperature. This will be a bit trickier. You can find the heat capacity from the previous plot by looking at the slope. \begin{align} C_p &= \left(\frac{\partial Q}{\partial T}\right)_p \end{align} This is what is called the heat capacity, which is the amount of energy needed to change the temperature by a given amount. The \(p\) subscript means that your measurement was made at constant pressure. This heat capacity is actually the total heat capacity of everything you put in the calorimeter, which includes the resistor and thermometer.
3. Specific heat From your plot of \(C_p(T)\), work out the heat capacity per unit mass of water. You may assume the effect of the resistor and thermometer are negligible. How does your answer compare with the prediction of the Dulong-Petit law?
4. Latent heat of fusion What did the temperature do while the ice was melting? How much energy was required to melt the ice in your calorimeter? How much energy was required per unit mass? per molecule?
5. Entropy of fusion The change in entropy is easy to measure for a reversible isothermal process (such as the slow melting of ice), it is just \begin{align} \Delta S &= \frac{Q}{T} \end{align} where \(Q\) is the energy thermally added to the system and \(T\) is the temperature in Kelvin. What is was change in the entropy of the ice you melted? What was the change in entropy per molecule? What was the change in entropy per molecule divided by Boltzmann's constant?
6. Entropy for a temperature change Choose two temperatures that your water reached (after the ice melted), and find the change in the entropy of your water. This change is given by \begin{align} \Delta S &= \int \frac{{\mathit{\unicode{273}}} Q}{T} \\ &= \int_{t_i}^{t_f} \frac{P(t)}{T(t)}dt \end{align} where \(P(t)\) is the heater power as a function of time and \(T(t)\) is the temperature, also as a function of time.

Use integration to find the total mass of the icecream in a packed cone (both the cone and the hemisphere of icecream on top).

Consider one mole of an ideal monatomic gas at 300K and 1 atm. First, let the gas expand isothermally and reversibly to twice the initial volume; second, let this be followed by an isentropic expansion from twice to four times the original volume.

1. How much heat (in joules) is added to the gas in each of these two processes?

2. What is the temperature at the end of the second process?

3. Suppose the first process is replaced by an irreversible expansion into a vacuum, to a total volume twice the initial volume. What is the increase of entropy in the irreversible expansion, in J/K?

1. Find the chemical potential of an ideal monatomic gas in two dimensions, with \(N\) atoms confined to a square of area \(A=L^2\). The spin is zero.

2. Find an expression for the energy \(U\) of the gas.

3. Find an expression for the entropy \(\sigma\). The temperature is \(kT\).

Inhomogeneous, linear ODEs with constant coefficients are among the most straigtforward to solve, although the algebra can get messy. This content should have been covered in your Differential Equations course (MTH 256 or equiv.). If you need a review, please see: The Method for Inhomogeneous Equations or your differential equations text.

For the following inhomogeneous linear equation with constant coefficients, find the general solution for \(y(x)\).

\[y''+2y'-y=\sin{x} +\cos{2x}\]

The general solution of the homogeneous differential equation

\[\ddot{x}-\dot{x}-6 x=0\]

is

\[x(t)=A\, e^{3t}+ B\, e^{-2t}\]

where \(A\) and \(B\) are arbitrary constants that would be determined by the initial conditions of the problem.

1. Find a particular solution of the inhomogeneous differential equation \(\ddot{x}-\dot{x}-6 x=-25\sin(4 t)\).

2. Find the general solution of \(\ddot{x}-\dot{x}-6 x=-25\sin(4 t)\).

3. Some terms in your general solution have an undetermined coefficients, while some coefficients are fully determined. Explain what is different about these two cases.

4. Find a particular solution of \(\ddot{x}-\dot{x}-6 x=12 e^{-3 t}\)

5. Find the general solution of \(\ddot{x}-\dot{x}-6 x=12 e^{-3 t}-25\sin(4 t)\)

   How is this general solution related to the particular solutions you found in the previous parts of this question?

   Can you add these particular solutions together with arbitrary coefficients to get a new particular solution?

6. Sense-making: Check your answer; Explicitly plug in your final answer in part (e) and check that it satisfies the differential equation.

1. Show that the first property of inner products \[\left\langle {f}\middle|{g}\right\rangle =\left\langle {g}\middle|{f}\right\rangle ^*\] is satisfied for this definition.
2. Show that the second property of inner products \[\left\langle {f}\right|\Big(\lambda\left|{g}\right\rangle + \mu \left|{h}\right\rangle \Big) = \lambda\left\langle {f}\middle|{g}\right\rangle +\mu\left\langle {f}\middle|{h}\right\rangle \] is satisfied for this definition.